Discrete polarization state spectroscopic ellipsometer system and method of use

ABSTRACT

A spectroscopic ellipsometer system comprising a plurality of individual sources which are sequentially energized to provide a sequence of beams, each of different polarization state but directed along a common locus toward a sample. The preferred spectroscopic ellipsometer system has no parts which move during data collection, and it provides a progressive plurality of sequentially discrete, rather than continuously varying, polarization states.

This application is also a Continuation-in-Part of application Ser. No.09/945,962 Filed Sep. 4, 2001, and therevia of application Ser. Nos.09/517,125 Filed Feb. 29, 2000; now abandoned; and of 09/246,888 filedFeb. 8, 1999, (now U.S. Pat. No. 6,084,675); and further of: Ser. No.09/225,118 (now U.S. Pat. No. 6,084,674); Ser. No. 09/223,822 (now U.S.Pat. No. 6,118,537); Ser. No. 09/232,257 (now U.S. Pat. No. 6,141,102);Ser. No. 09/225,371 (now U.S. Pat. No. 6,100,981); Ser. No. 09/225,076(now U.S. Pat. No. 5,963,325) which application depended from Ser. No.08/997,311 filed Dec. 23, 1997, (now U.S. Pat. No. 5,946,098). Further,via the Ser. No. 09/246,888 application, this application is aContinuation-In-Part of: Ser. No. 08/912,211 filed Aug. 15, 1997, (nowU.S. Pat. No. 5,872,630), which Continued-In-Part from Ser. No.08/530,892 filed Sep. 20, 1995, (now U.S. Pat. No. 5,666,201); and andis also a CIP of Ser. No. 08/618,820 filed Mar. 20, 1996, (now U.S. Pat.No. 5,706,212). In addition, priority is Claimed from: Ser. No.09/162,217 filed Sep. 29, 1998 via above applications. This applicationalso Claims benefit of Provisional Application Ser. No. 60/229,755 filedSep. 5, 2000 in addition to, via the 962 application, ProvisionalApplication Ser. Nos. 60/229,755 Filed Sep. 5, 2000, and 60/438,187Filed Jan. 7, 2003.

TECHNICAL FIELD

The present invention relates to ellipsometer systems, as well asmethods of calibration and use thereof. More particularly the presentinvention is, in its preferred embodiment, a spectroscopic ellipsometersystem comprising a plurality of individual sources which aresequentially energized to provide a sequence of beams, each thereofbeing of a different polarization state, but directed along a commonlocus toward a sample. The preferred spectroscopic ellipsometer of thepresent invention system has no parts which move during data collectionand provides a progressive plurality of sequentially discrete, ratherthan continuously varying, polarization states.

BACKGROUND

The practice of ellipsometry is well established as a non-destructiveapproach to determining characteristics of sample systems, and can bepracticed in real time. The topic is well described in a number ofpublications, one such publication being a review paper by Collins,titled “Automatic Rotating Element Ellipsometers: Calibration, Operationand Real-Time Applications”, Rev. Sci. Instrum., 61(8) (1990).

In general, modern practice of ellipsometry typically involves causing aspectroscopic beam of electromagnetic radiation, in a known state ofpolarization, to interact with a sample system at least one angle ofincidence with respect to a normal to a surface thereof, in a plane ofincidence. (Note, a plane of incidence contains both a normal to asurface of an investigated sample system and the locus of said beam ofelectromagnetic radiation). Changes in the polarization state of saidbeam of electromagnetic radiation which occur as a result of saidinteraction with said sample system are indicative of the structure andcomposition of said sample system. The practice of ellipsometry furtherinvolves proposing a mathematical model of the ellipsometer system andthe sample system investigated by use thereof, and experimental data isthen obtained by application of the ellipsometer system. This istypically followed by application of a square error reducingmathematical regression to the end that parameters in the mathematicalmodel which characterize the sample system are evaluated, such that theobtained experimental data, and values calculated by use of themathematical model, are essentially the same.

A typical goal in ellipsometry is to obtain, for each wavelength in, andangle of incidence of said beam of electromagnetic radiation caused tointeract with a sample system, sample system characterizing PSI andDELTA values, (where PSI is related to a change in a ratio of magnitudesof orthogonal components r_(p)/r_(s) in said beam of electromagneticradiation, and wherein DELTA is related to a phase shift entered betweensaid orthogonal components r_(p) and r_(s)), caused by interaction withsaid sample system:PSI=|r _(p) /r _(s)|; andDELTA=(Δr _(p) −Δr _(s)).

As alluded to, the practice of ellipsometry requires that a mathematicalmodel be derived and provided for a sample system and for theellipsometer system being applied. In that light it must be appreciatedthat an ellipsometer system which is applied to investigate a samplesystem is, generally, sequentially comprised of:

-   -   a. a Source of a beam electromagnetic radiation;    -   b. a Polarizer element;    -   c. optionally a compensator element;    -   d. (additional element(s));    -   e. a sample system;    -   f. (additional element(s));    -   g. optionally a compensator element;    -   h. an Analyzer element; and    -   i. a Spectroscopic Detector System.        Each of said components b.-i. must be accurately represented by        a mathematical model of the ellipsometer system along with a        vector which represents a beam of electromagnetic radiation        provided from said source of a beam electromagnetic radiation,        Identified in a. above)

Various conventional ellipsometer configurations provide that aPolarizer, Analyzer and/or Compensator(s) can be rotated during dataacquisition, and are describe variously as Rotating Polarizer (RPE),Rotating Analyzer (RAE) and Rotating Compensator (RCE) EllipsometerSystems. As described elsewhere in this Specification, the presentinvention breaks with this convention and provides that no element becontinuously rotated during data acquisition but rather that a sequenceof discrete polarization states be imposed during data acquisition. Thisapproach allows eliminating many costly components from conventionalrotating element ellipsometer systems, and, hence, production of an“Ultra-Low-Cost” ellipsometer system. It is noted, that nullingellipsometers also exist in which elements therein are rotatable in use,rather than rotating. Generally, use of a nulling ellipsometer systeminvolves imposing a linear polarization state on a beam ofelectromagnetic radiation with a polarizer, causing the resultingpolarized beam of electromagnetic radiation to interact with a samplesystem, and then adjusting an analyzer to an azimuthal azimuthal anglewhich effectively cancels out the beam of electromagnetic radiationwhich proceeds past the sample system. The azimuthal angle of theanalyzer at which nulling occurs provides insight to properties of thesample system.

It is further noted that reflectometer systems are generallysequentially comprised of:

-   -   a. a Source of a beam electromagnetic radiation;    -   d. (optional additional element(s));    -   e. a sample system;    -   f. (optional additional element(s));    -   i. a Spectroscopic Detector System;        and that reflectometer systems monitor changes in intensity of a        beam of electromagnetic radiation caused to interact with a        sample system. That is, the ratio of, and phase angle between,        orthogonal components in a polarized beam are not of direct        concern.

Continuing, in use, data sets can be obtained with an ellipsometersystem configured with a sample system present, sequentially for caseswhere other sample systems are present, and where an ellipsometer systemis configured in a straight-through configuration wherein a beam ofelectromagnetic radiation is caused to pass straight through theellipsometer system without interacting with a sample system.Simultaneous mathematical regression utilizing multiple data sets canallow evaluation of sample system characterizing PSI and DELTA valuesover a range of wavelengths. The obtaining of numerous data sets with anellipsometer system configured with, for instance, a sequence of samplesystems present and/or wherein a sequential plurality of polarizationstates are imposed on an electromagnetic beam caused to interacttherewith, can allow system calibration of numerous ellipsometer systemvariables.

Patents of which the Inventor is aware include those to Woollam et al,U.S. Pat. No. 5,373,359, patent to Johs et al. U.S. Pat. No. 5,666,201and patent to Green et al., U.S. Pat. No. 5,521,706, and patent to Johset al., U.S. Pat. No. 5,504,582 are disclosed for general information asthey pertain to ellipsometer systems.

U.S. Pat. No. 6,268,917 to Johs discloses a system for combining aplurality of polychromatic beams into a single beam which has a smootherintensity vs. wavelength plot.

Further patents of which the Inventor is aware include U.S. Pat. Nos.5,757,494 and 5,956,145 to Green et al., in which are taught a methodfor extending the range of Rotating Analyzer/Polarizer ellipsometersystems to allow measurement of DELTA'S near zero (0.0) andone-hundred-eighty (180) degrees, and the extension of modulator elementellipsometers to PSI'S of forty-five (45) degrees. Said patentsdescribes the presence of a variable, transmissive, bi-refringentcomponent which is added, and the application thereof during dataacquisition to enable the identified capability.

A patent to Thompson et al. U.S. Pat. No. 5,706,212 is also disclosed asit teaches a mathematical regression based double Fourier seriesellipsometer calibration procedure for application, primarily, incalibrating ellipsometers system utilized in infrared wavelength range.Bi-refringent, transmissive window-like compensators are described aspresent in the system thereof, and discussion of correlation ofretardations entered by sequentially adjacent elements which do notrotate with respect to one another during data acquisition is describedtherein.

A patent to He et al., U.S. Pat. No. 5,963,327 is disclosed as itdescribes an ellipsometer system which enables providing a polarizedbeam of electromagnetic radiation at an oblique angle-of-incidence to asample system in a small spot area.

A patent to Johs et al., U.S. Pat. No. 5,872,630 is disclosed as itdescribes an ellipsometer system in which an analyzer and polarizer aremaintained in a fixed in position during data acquisition, while acompensator is caused to continuously rotate.

A patent to Coates et al., U.S. Pat. No. 4,826,321 is disclosed as itdescribes applying a reflected monochromatic beam of plane polarizedelectromagnetic radiation at a Brewster angle of incidence to a samplesubstrate to determine the thickness of a thin film thereupon. Thispatent also describes calibration utilizing two sample substrates, whichhave different depths of surface coating.

Other patents which describe use of reflected electromagnetic radiationto investigate sample systems are U.S. Pat. Nos. RE 34,783, 4,373,817,and 5,045,704 to Coates; and 5,452,091 to Johnson.

A patent to Biork et al., U.S. Pat. No. 4,647,207 is disclosed as itdescribes an ellipsometer system which has provision for sequentiallypositioning a plurality of reflective polarization state modifiers in abeam of electromagnetic radiation. While said 207 patent mentionsinvestigating a sample system in a transmission mode, no mention orsuggestion is found for utilizing a plurality of transmittingpolarization state modifiers, emphasis added. U.S. Pat. Nos. 4,210,401;4,332,476 and 4,355,903 are also identified as being cited in the 207patent. It is noted that systems as disclosed in these patents,(particularly in the 476 patent), which utilize reflection from anelement to modify a polarization state can, if such an element is anessential duplicate of an investigated sample and is rotated ninetydegrees therefrom, the effect of the polarization state modifyingelement on the electromagnetic beam effect is extinguished by thesample.

A patent to Mansuripur et al., U.S. Pat. No. 4,838,695 is disclosed asit describes an apparatus for measuring reflectivity.

patents to Rosencwaig et al., U.S. Pat. Nos. 4,750,822 and 5,595,406 arealso identified as they describe systems which impinge electromagneticbeams onto sample systems at oblique angles of incidence. The 406 patentprovides for use of multiple wavelengths and multiple angles ofincidence. For similar reasons U.S. Pat. No. 5,042,951 to Gold et al. isalso disclosed.

A patent to Osterberg, U.S. Pat. No. 2,700,918 describes a microscopewith variable means for increasing the visibility of optical images,partially comprised of discrete bi-refringent plates which can bepositioned in the pathway between an eyepiece and an observed object.Other patents identified in a Search which identified said 918 patentare U.S. Pat. No. 3,183,763 to Koester; U.S. Pat. No. 4,105,338 toKuroha; U.S. Pat. No. 3,992,104 to Watanabe and a Russian Patent, No. SU1518728. Said other patents are not believed to be particularlyrelevant, however.

A patent, U.S. Pat. No. 5,329,357 to Bernoux et al. is also identifiedas it Claims use of fiber optics to carry electromagnetic radiation toand from an ellipsometer system which has at least one polarizer oranalyzer which rotates during data acquisition. It is noted that if boththe polarizer and analyzer are stationary during data acquisition thatthis patent is not controlling where electromagnetic radiation carryingfiber optics are present.

As present invention preferred practice is to utilize a spectroscopicsource of electromagnetic radiation with a relatively flat spectrum overa large range of wavelengths U.S. Pat. No. 5,179,462 to Kageyama et al.is identified as it provides a sequence of three electromagnetic beamcombining dichroic mirrors in an arrangement which produces an outputbeam of electromagnetic radiation that contains wavelengths from each offour sources of electromagnetic radiation. Each electromagnetic beamcombining dichroic mirror is arranged so as to transmit a first inputbeam of electromagnetic radiation, comprising at least a firstwavelength content, therethrough so that it exits a second side of saidelectromagnetic beam combining dichroic mirror, and to reflect a secondbeam of electromagnetic radiation, comprising an additional wavelengthcontent, from said second side of said electromagnetic beam combiningdichroic mirror in a manner that a single output beam of electromagneticradiation is formed which contains the wavelength content of bothsources of electromagnetic radiation. The sources of electromagneticradiation are described as lasers in said 462 patent. Another patent,U.S. Pat. No. 5,296,958 to Roddy et al., describes a similar systemwhich utilizes Thompson Prisms to similarly combine electromagneticbeams for laser source. U.S. Pat. Nos. 4,982,206 and 5,113,279 toKessler et al. and Hanamoto et al. respectively, describe similarelectromagnetic electromagnetic beam combination systems in laserprinter and laser beam scanning systems respectively. Another patent,U.S. Pat. No. 3,947,688 to Massey, describes a method of generatingtuneable coherent ultraviolet light, comprising use of anelectromagnetic electromagnetic beam combining system. A patent toMiller et al., U.S. Pat. No. 5,155,623, describes a system for combininginformation beams in which a mirror comprising alternating regions oftransparent and reflecting regions is utilized to combine transmittedand reflected beams of electromagnetic radiation into a single outputbeam. A patent to Wright, U.S. Pat. No. 5,002,371 is also mentioned asdescribing a beam splitter system which operates to separate “P” and “S”orthogonal components in a beam of polarized electromagnetic radiation.Another patent, U.S. Pat. No. 6,384,916 to Furtak is disclosed as itdescribes a parallel detecting spectroscopic ellipsometer having nomoving parts.

In addition to the identified patents, certain Scientific papers arealso identified.

A paper by Johs, titled “Regression Calibration Method for RotatingElement Ellipsometers”, Thin Solid Films, 234 (1993) is also disclosedas it describes a mathematical regression based approach to calibratingellipsometer systems.

Another paper, by Gottesfeld et al., titled “Combined Ellipsometer andReflectometer Measurements of Surface Processes on Nobel MetalsElectrodes”, Surface Sci., 56 (1976), is also identified as describingthe benefits of combining ellipsometry and reflectometry.

A paper by Smith, titled “An Automated Scanning Ellipsometer”, SurfaceScience, Vol. 56, No. 1. (1976), is also mentioned as it describes anellipsometer system which does not require any moving, (eg. rotating),elements during data acquisition.

Four additional papers by Azzam and Azzam et al. are also identified andarc titled:

-   -   “Multichannel Polarization State Detectors For Time-Resolved        Ellipsometry”, Thin Solid Film, 234 (1993); and    -   “Spectrophotopolarimeter Based On Multiple Reflections In A        Coated Dielectric Slab”, Thin Solid Films 313 (1998); and    -   “General Analysis And Optimization Of The Four-Detector        Photopolarimeter”, J. Opt. Soc. Am., A, Vol. 5, No. 5 (May        1988); and    -   “Accurate Calibration Of Four-Detector Photopolarimeter With        Imperfect Polarization Optical Elements”, J. Opt. Soc. Am., Vol.        6, No. 10, (October 1989);        as they describe alternative approaches concerning the goal of        the present invention.

Even in view of relevant prior art, there remains need for a low costspectroscopic ellipsometer system which:

-   -   has no moving parts during data acquisition;    -   utilizes a plurality of separate source means to effect a        plurality of sequential discrete, rather than continuously        varying, polarization states during said data acquisition; and    -   optionally comprises a beam splitting analyzer, and multiple        detector systems.

In addition there remains need for:

-   -   a calibration procedure for said spectroscopic ellipsometer        system which involves the gathering of spectroscopic data at a        plurality of discrete polarization states for each of some        number of sample systems; and    -   a method for applying the disclosed system in sample        investigation.

The present invention responds to said identified needs.

DISCLOSURE OF THE INVENTION

The preferred embodiment of the disclosed invention is a low cost samplesystem investigation system comprising:

-   -   a) a plurality of electromagnetic radiation sources, each        thereof optionally having polarization state setting means        functionally associated therewith;    -   b) a means for accepting at least two electromagnetic beams        which approach along different loci, and providing an        electromagnetic beam which exits therefrom along a single locus;    -   c) a stage for supporting a sample system; and    -   d) at least one detector system.

Said at least first means for accepting at least two electromagneticbeams which approach along different loci, and providing anelectromagnetic beam which exits therefrom along a single locus, ispositioned with respect to at least two of said plurality of sources ofelectromagnetic radiation such that a beam of electromagnetic radiationfrom either thereof, when it is energized, enters thereinto and emergestherefrom along a locus which is directed toward a sample system placedon said stage for supporting a sample system.

Said at least one detector system is positioned to intercept a beamwhich emerges from the sample system on said stage for supporting asample system after said beam of electromagnetic radiation interactstherewith.

While not a requirement, the preferred arrangement provides that thesample system investigation system each of the plurality ofelectromagnetic radiation sources has polarization state setting meansfunctionally associated therewith. Said polarization state setting meansassociated with said first electromagnetic radiation source is set toprovide a different polarization state on a beam of electromagneticradiation emerging therefrom than does the polarization state settingmeans associated with said second electromagnetic radiation sourceimpose on a beam of electromagnetic radiation emerging from said secondelectromagnetic radiation source. While all of the plurality ofelectromagnetic radiation sources can be selected to provide a beam ofpolychromatic electromagnetic radiation, at least one source can providesubstantially monochromatic electromagnetic radiation, and it is notedthat where different sources of the plurality of electromagneticradiation sources provide different wavelengths, that alone candistinguish the sources without need for the optional differentpolarization states being effected.

With the system described, it should be appreciate that a method ofanalyzing a sample system comprising the steps of:

A) providing a sample system investigation system comprising:

-   -   a) a plurality of electromagnetic radiation sources, each        thereof optionally having polarization state setting means        functionally associated therewith;    -   b) a means for accepting at least two electromagnetic beams        which approach along different loci, and providing an        electromagnetic beam which exits therefrom along a single locus;    -   c) a stage for supporting a sample system;    -   d) at least one detector system;    -   e) computation means;        said at least first means for accepting at least two        electromagnetic beams which approach along different loci, and        providing an electromagnetic beam which exits therefrom along a        single locus, being positioned with respect to at least two of        said plurality of sources of electromagnetic radiation such that        a beam of electromagnetic radiation from either thereof, when it        is energized, enters thereinto and emerges therefrom along a        locus which is directed toward a sample system placed on said        stage for supporting a sample system;    -   said at least one detector system being positioned to intercept        a beam which emerges from the sample system on said stage for        supporting a sample system after said beam interacts therewith;

B) energizing one of said sources of electromagnetic radiation andaccumulating data from said at least one detector system;

C) optionally energizing a second of said sources of electromagneticradiation and accumulating data from said at least one detector system;

D) optionally energizing a third of said sources of electromagneticradiation and accumulating data from said at least one detector system;

E) optionally energizing a fourth of said sources of electromagneticradiation and accumulating data from said at least one detector system;

F) applying said computation means to analyze said sample systemutilizing said accumulated data.

Said method, in the step of providing a sample system investigationsystem can involve providing a sample system investigation systemcharacterized by a selection from the group consisting of:

-   -   none of said plurality of electromagnetic radiation sources has        polarization state setting means functionally associated        therewith;    -   at least one of said plurality of electromagnetic radiation        sources has polarization state setting means functionally        associated therewith;    -   at least one of said plurality of electromagnetic radiation        sources provides a beam of substantially monochromatic        electomagnetic radiation;    -   at least one of said plurality of electromagnetic radiation        sources provides a beam of polychromatic electomagnetic        radiation;    -   at least a first and a second of said plurality of        electromagnetic radiation sources each have polarization state        setting means functionally associated therewith, the        polarization state setting means functionally associated with        said first electromagnetic radiation source being set to provide        a different polarization state to a beam of electromagnetic        radiation emerging therefrom than does the polarization state        setting means functionally associated with said second        electromagnetic radiation source impose on a beam of        electromagnetic radiation emerging from said second        electromagnetic radiation source.

Where said method provides that at least a first and a second of saidplurality of electromagnetic radiation sources each have polarizationstate setting means functionally associated therewith, the polarizationstate setting means associated with said first electromagnetic radiationsource being set to provide a different polarization state on a beam ofelectromagnetic radiation emerging therefrom than does the polarizationstate setting means associated with said second electromagneticradiation source impose on a beam of electromagnetic radiation emergingfrom said second electromagnetic radiation source, and in which said atleast first and second of said plurality of electromagnetic radiationsources are sequentially energized in steps B) and (C).

The preferred embodiment of the disclosed sample system investigationsystem can comprise:

-   -   a) at least a first and a second source of electromagnetic        radiation, each thereof having polarization state setting means        functionally associated therewith;    -   b) at least a first electromagnetic beam combining means;    -   c) a stage for supporting a sample system;    -   d) analyzer means; and    -   e) at least one detector system.        Said at least a first electromagnetic beam combining means is        positioned with respect to first and second sources of        electromagnetic radiation such that a polarized beam of        electromagnetic radiation from said first source of        electromagnetic radiation, when it is energized, passes through        said at least a first electromagnetic beam combining means, and        such that a polarized beam of electromagnetic radiation from        said second source of electromagnetic radiation, when it is        energized, reflects from said at least a first electromagnetic        beam combining means such that a beam of electromagnetic        radiation exiting said first electromagnetic beam combining        means proceeds along a locus which is directed toward a sample        system placed on said stage for supporting a sample system.

Said at least one detector system comprising said analyzer means andbeing positioned to intercept a beam which emerges from the samplesystem on said stage for supporting a sample system after interactiontherewith.

Said sample system investigation system can further comprise:

-   -   f) a third and a fourth source of electromagnetic radiation,        each thereof having polarization state setting means        functionally associated therewith;    -   g) a second electromagnetic beam combining means; and    -   h) a third electromagnetic beam combining means.        Said third electromagnetic beam combining means is positioned        such that said beam of electromagnetic beam exiting said first        electromagnetic beam combining means along a locus which is        directed toward a sample system placed on said stage for        supporting a sample system, passes therethrough before        proceeding toward said sample system. Said second        electromagnetic beam combining means is positioned with respect        to said third and fourth sources of electromagnetic radiation        such that a polarized beam of electromagnetic radiation from        said third source of electromagnetic radiation, when it is        energized, passes through said second electromagnetic beam        combining means, and such that a polarized beam of        electromagnetic radiation from said fourth source of        electromagnetic radiation, when it is energized, reflects from        said second electromagnetic beam combining means. In use, a beam        of electromagnetic radiation exiting said second electromagnetic        beam combining means along a locus which is directed toward said        third electromagnetic beam combining means, reflects off thereof        and proceed toward said sample system Said at least one detector        system which comprises analyzer means, is positioned to        intercept a beam which emerges from the sample system on said        stage for supporting a sample system after interaction        therewith.

Said sample system investigation system preferably provides that thepolarization state setting means functionally associated with said firstand second sources of electromagnetic radiation are at azimuthalorientations offset from one another, and that said azimuthal settingsare offset from the third and fourth sources of electromagneticradiation, which are at azimuthal orientations offset from one another.Preferably the azimuthal offsets, first to second, second to third, andthird to fourth polarization state setting means are at azimuthalorientations which are offset 45 degrees from one another.

The preferred sources of electromagnetic radiation comprise lightemitting diodes, and said first, second, third and fourth sources ofelectromagnetic radiation can variously comprise light emitting diodeswhich emit various colors, or a white spectrum.

The sample system investigation system contains a Detector, typicallypreceded by a Rotatable Analyzer which is set, and remains stationary,during data acquisition.

A preferred sample system investigation system contains a polarizationstate dependent beam splitter and two detectors, each of which receive adifferent beam emerging from said beam splitter.

A disclosed invention method of analyzing a sample system comprises thesteps of:

A) providing a sample system investigation system comprising:

-   -   a) at least a first and a second source of electromagnetic        radiation, each thereof having polarization state setting means        functionally associated therewith, said polarization state        setting means functionally associated with said first and said        second sources of electromagnetic radiation being at azimuthal        orientations offset from one another;    -   b) first electromagnetic beam combining means;    -   c) a stage for supporting a sample system;    -   d) analyzer means;    -   e) at least one detector system;    -   f) computational means.        as described above; then in either order practicing the        following steps:

B) energizing said first source of electromagnetic radiation andaccumulating data from said at least one detector system; and

C) energizing said second source of electromagnetic radiation andaccumulating data from said at least one detector system;

F) applying said computation means to analyze said sample systemutilizing said accumulated data.

Another recitation of a disclosed invention method of analyzing a samplesystem comprising the steps of:

A) providing a sample system investigation system comprising:

-   -   a) first, second, third and fourth sources of electromagnetic        radiation, each thereof having polarization state setting means        functionally associated therewith, said polarization state        setting means functionally associated with said first, second,        third and fourth sources of electromagnetic radiation being at        orientations offset from one another;    -   b) first, second and third electromagnetic beam combining means;    -   c) a stage for supporting a sample system;    -   d) analyzer means;    -   e) at least one detector system;    -   f) a computation means.        Said first, second, third and forth sources of electromagnetic        radiation and said first, second and third beam combining means        being oriented as described above, and said at least one        detector system which comprises said analyzer means also being        positioned to intercept a beam which emerges from the sample        system, as described above. Said method then involves, in any        functional order practicing at least two steps selected from the        group consisting of:

B) energizing said first source of electromagnetic radiation andaccumulating data from said at least one detector system;

C) energizing said second source of electromagnetic radiation andaccumulating data from said at least one detector system;

D) energizing said third source of electromagnetic radiation andaccumulating data from said at least one detector system;

E) energizing said fourth source of electromagnetic radiation andaccumulating data from said at least one detector system; and

F) applying said computation means to analyze said sample systemutilizing said accumulated data.

The sample system investigation system can further comprise at least onecompensator prior to and/or after the stage for supporting a samplesystem.

As the disclosed invention is a low cost spectroscopic ellipsometersystem, additional low cost spectroscopic ellipsometer systems whichalso provide a sequence of discrete polarization states are alsodescribed herein for contrast and comparison. Such an alternative lowcost spectroscopic ellipsometer system, (which has parts which moveduring data acquisition), comprises:

-   -   a source of polychromatic electromagnetic radiation;    -   a polarizer which is fixed in position during data acquisition;    -   a stage for supporting a sample system;    -   an analyzer which is fixed in position during data acquisition;        and    -   a multi-element spectroscopic detector system.        In addition, said ellipsometer system further comprises at least        one means for discretely, sequentially, modifying a polarization        state of a beam of electromagnetic radiation through a plurality        of polarization states. The at least one means for discretely,        sequentially, modifying a polarization state of a beam of        electromagnetic radiation through a plurality of polarization        states, is positioned between said polarizer and said stage for        supporting a sample system, and/or and between said stage for        supporting a sample system and said analyzer, and so that said        beam of electromagnetic radiation transmits through a        polarization state modifier element thereof in use.

Said alternative low cost spectroscopic ellipsometer system can alsocomprise a combination spectroscopic reflectometer/ellipsometer systembasically comprising:

-   -   a source of polychromatic electromagnetic radiation;    -   a stage for supporting a sample system;    -   a multi-element spectroscopic detector system.        The combination spectroscopic reflectometer/ellipsometer system        further comprises, in the ellipsometer system portion thereof, a        polarizer, (which is fixed in position during data acquisition),        present between the source of polychromatic electromagnetic        radiation and the stage for supporting a sample system, and an        analyzer, (which is fixed in position during data acquisition),        present between the stage for supporting a sample system and the        multi-element spectroscopic detector system. The ellipsometer        system also comprises at least one means for discretely,        sequentially, modifying a polarization state of a beam of        electromagnetic radiation through a plurality of polarization        states present between said polarizer and said stage for        supporting a sample system, and/or between said stage for        supporting a sample system and said analyzer, and positioned so        that said beam of electromagnetic radiation transmits through a        polarization state modifier element therein during use.

Additionally, the combination spectroscopic reflectometer/ellipsometersystem is configured such that a polychromatic beam of electromagneticradiation provided by said source of polychromatic electromagneticradiation can, optionally, be directed to interact with a sample systempresent on said stage for supporting a sample system without anypolarization state being imposed thereupon, and such that apolychromatic beam of electromagnetic radiation also provided by saidsource of polychromatic electromagnetic radiation can be, optionallysimultaneously, directed to interact with a sample system present onsaid stage for supporting a sample system after a polarization state hasbeen imposed thereupon. The polychromatic beam of electromagneticradiation without any polarization state imposed thereupon, whendirected to interact with a sample system present on said stage forsupporting a sample system, is typically caused to approach said samplesystem at an oblique angle-of-incidence which is between a sample systemBrewster angle and a normal to the surface of the sample system.Further, the polychromatic beam of electromagnetic radiation provided bysaid source of polychromatic electromagnetic radiation upon which apolarization state has been imposed, is typically directed to interactwith a sample system present on said stage for supporting a samplesystem at an angle near the Brewster angle of the sample system beinginvestigated. Either, or both, the polychromatic beam(s) ofelectromagnetic radiation provided by said source of polychromaticelectromagnetic radiation, upon which is imposed a polarization state orupon which no polarization state is imposed, is preferably directed tointeract with a sample system present on said stage for supporting asample system via a fiber optic means.

As one non-limiting example, the spectroscopic ellipsometer system atleast one means for discretely, sequentially, modifying a polarizationstate of a beam of electromagnetic radiation provided by said source ofpolychromatic electromagnetic radiation through a plurality ofpolarization states, can comprise an essentially circular “wheel”element with a plurality of discrete polarization state modifierelements mounted thereupon, on the perimeter thereof, and projectingperpendicularly to a surface of said essentially circular “wheel”. Theessentially circular “wheel” element further comprises a means forcausing rotation about a normal to said surface thereof, such that inuse said essentially circular “wheel” element is caused to rotate toposition a discrete polarization state modifier element such that thebeam of electromagnetic radiation, provided by said source ofpolychromatic electromagnetic radiation, passes therethrough. That is,the wheel is moved during data collection.

As another non-limiting example, the spectroscopic ellipsometer systemat least one means for discretely, sequentially, modifying apolarization state of a beam of electromagnetic radiation provided bysaid source of polychromatic electromagnetic radiation through aplurality of polarization states, can comprise a plurality of discretepolarization state modifier elements mounted on a slider element whichis mounted in a guide providing element. During use sliding the sliderelement to the right or left serves to position a discrete polarizerelement such that said a beam of electromagnetic radiation, provided bysaid source of polychromatic electromagnetic radiation, passestherethrough.

It is further disclosed that a system for providing an output beam ofpolychromatic electromagnetic radiation which has a relatively broad andflattened Intensity vs. Wavelength characteristic over a wavelengthspectrum utilized in said disclosed invention systems can be applied inthe disclosed invention systems. The reason for doing so is to providean output beam of polychromatic electromagnetic radiation which issubstantially a comingled composite of a plurality of input beams ofpolychromatic electromagnetic radiation which individually do notprovide as relatively broad and flattened a intensity vs. wavelengthcharacteristic over said wavelength spectrum, as does said outputcomingled composite beam of polychromatic electromagnetic radiation.(Note, where colored (LED's) are the sources, said system can utilizetheir substantially monochromatic outputs as input thereto, perhaps incombination with a white wavelength range (LED)). The system forproviding an output beam of polychromatic electromagnetic radiation,which has a relatively broad and flattened intensity vs. wavelengthcharacteristic over a wavelength spectrum, comprises:

-   -   a. at least a first and a second source of polychromatic        electromagnetic radiation; and    -   b. at least a first electromagnetic beam combining means        comprising a plate, (eg. uncoated fused silica or glass etc.        such that transmission characteristics thereof are determined by        angle-of-incidence and polarization state of a beam of        electromagnetic radiation).        The at least a first electromagnetic beam combining means is        positioned with respect to said first and second sources of        electromagnetic radiation such that a beam of electromagnetic        radiation from said first source of electromagnetic radiation        passes through said at least a first electromagnetic beam        combining means, and such that a beam of electromagnetic        radiation from said second source of electromagnetic radiation        reflects from said at least a first electromagnetic beam        combining means and is comingled with said beam of        electromagnetic radiation from said first source of        electromagnetic radiation which passes through said at least a        first electromagnetic beam combining means. The resultant beam        of polychromatic electromagnetic radiation exiting the first        electromagnetic beam combining means is substantially an output        beam of polychromatic electromagnetic radiation which has a        relatively broad and flattened intensity vs. wavelength over a        wavelength spectrum, comprising said comingled composite of a        plurality of input beams of electromagnetic radiation which        individually do not provide such a relatively broad and        flattened intensity vs. wavelength over a wavelength spectrum        characteristic. Said system for providing an output beam of        polychromatic electromagnetic radiation which has a relatively        broad and flattened intensity vs. wavelength characteristic over        a wavelength spectrum can also be optionally further        characterized by a third source of electromagnetic radiation,        and a second electromagnetic beam combining (BCM) means        comprising an uncoated plate, (eg. fused silica or glass etc.        such that transmission characteristics thereof are determined by        angle-of-incidence and polarization state of a beam of        electromagnetic radiation). The second electromagnetic beam        combining means, when present, is positioned with respect to        said comingled beam of polychromatic electromagnetic radiation        which has a relatively broad and flattened intensity vs.        wavelength over a wavelength spectrum and which exits said at        least a first electromagnetic beam combining means, such that it        passes through said second electromagnetic beam combining means.        The second electromagnetic beam combining means is also        positioned with respect to the third source of electromagnetic        radiation, (when present), such that a beam of electromagnetic        radiation from said third source of electromagnetic radiation        reflects from said second electromagnetic beam combining means,        such that a second resultant beam of polychromatic        electromagnetic radiation which is substantially an output beam        of polychromatic electromagnetic radiation which has a        relatively even more broadened and flattened intensity vs.        wavelength over a wavelength spectrum, comprising said comingled        composite of a plurality of input beams of polychromatic        electromagnetic radiation from said first, second and third        sources, which first, second and third sources individually do        not provide such a relatively even more broadened and flattened        intensity vs. wavelength over a wavelength spectrum        characteristic.

At least one of said first and second, (when present), electromagneticbeam combining means can be pivotally mounted such that, for instance,the angle at which a beam of electromagnetic radiation from the secondsource of electromagnetic radiation reflects from the at least oneelectromagnetic beam combining means can be controlled to place itcoincident with the locus of a beam of electromagnetic radiationtransmitted therethrough. Pivot means providing two dimensional degreesof rotation freedom are preferred in this application. Further, wheresources of electromagnetic radiation can be moved, the pivot capabilitycan be utilized to allow use of optimum tilts of electromagnetic beamcombining means. That is, transmission and reflection characteristics ofan electromagnetic beam combining means vary with the angle of incidencea transmitted or reflected beam makes with respect thereto, and pivotmeans can allow adjusting tilt to optimize said characteristics.

Further, as the polarizer in the present invention spectroscopicellipsometer system remains essentially fixed in position during dataacquisition, it is noted that it is preferable that a source ofelectromagnetic radiation, and/or a present Polarizer or PolarizationState Generator be positioned or configured so as to pass predominately“S” Polarized electromagnetic radiation, as referenced to said beamcombining system. The reason for this is that the split between “S”polarization transmission and reflection components is less, as afunction of wavelength and electromagnetic beam angle-of-incidence tosaid beam combining means, when compared to that of the “P” components.The “P” component is far more affected, particularly around a Brewsterangle condition, hence, where an “S” component, with reference to a beamcombining system, is utilized, it is to be appreciated that variation inintensity of transmitted and reflected beams of electromagneticradiation output from the beam combining system, as functions ofwavelength and the angles of incidence of beams of electromagneticradiation from sources of said transmitted and reflected beams ofelectromagnetic radiation, is minimized, as compared to variation whichoccurs in “P” components.

Before discussing the Method of Calibration of the present inventionspectroscopic ellipsometer system, it is noted that the polarizer andanalyzer thereof, which are essentially fixed in position during dataacquisition, are not necessarily absolutely fixed in position. Saidpolarizer and analyzer are preferably what is properly termed“Rotatable”. That is they can be rotated to various positions by a userbetween data acquisitions, but they are not caused to be Rotating whiledata is being acquired. (Typical positioning of analyzer and polarizerazimuthal angles are plus or minus forty-five (+/−45) degrees).

Continuing, a present invention method of calibrating a spectroscopicellipsometer system comprising the steps of:

a. providing a spectroscopic ellipsometer system as described aboveherein, either independently or in functional combination with areflectometer system;

said method further comprising, in any functional order, the steps of:

b. for each of at least two ellipsometrically different sample systems,obtaining at least one multi-dimensional data set(s) comprisingintensity as a function of wavelength and a function of a plurality ofdiscrete polarization state settings, (which can be set by sequentiallyenergizing different sources, or by placing polarization state modifiersinto the path of a beam from a single source);

c. providing a mathematical model of the ellipsometer system and samplesystems utilized, including accounting for the polarization statesettings utilized in step b; and

d. by simultaneous mathematical regression onto said data sets,evaluating parameters in said mathematical model.

It is noted that the step of providing a means for discretely,sequentially, modifying a polarization state of a beam ofelectromagnetic radiation provided by said source of polychromaticelectromagnetic radiation through a plurality of polarization states,can involve:

-   -   providing at least one such means for discretely, sequentially,        modifying a polarization state of a beam of electromagnetic        radiation provided by a source of polychromatic electromagnetic        radiation through a plurality of polarization states that        changes the phase angle between orthogonal components of said        electromagnetic beam of radiation; or    -   providing at least one such means for discretely, sequentially,        modifying a polarization state of a beam of electromagnetic        radiation provided by a source of polychromatic electromagnetic        radiation through a plurality of polarization states, that        changes the magnitude intensity of least one orthogonal        component of said electromagnetic beam of radiation; or    -   providing at least one such means for discretely, sequentially,        modifying a polarization state of a beam of electromagnetic        radiation provided by a source of polychromatic electromagnetic        radiation through a plurality of polarization states, that        changes both the phase angle between orthogonal components and        the magnitude of least one orthogonal component of said        electromagnetic beam of radiation; or    -   energizing separate sources of electromagnetic radiation, each        of which has a different polarization state associated        therewith, all of which provide an electromagnetic beam which        approaches a sample system along a common locus via beam        combiners.

It is also mentioned that said method of calibrating a spectroscopicellipsometer system can require, in the step b. obtaining of at leastone multi-dimensional data set(s) comprising intensity as a function ofwavelength and a function of a plurality of discrete polarizationsettings, the obtaining of data from at least as many sample systems asare utilized discrete polarization state settings. However, ifpolarization state characteristics are parameterized, say as a functionof wavelength, and are expressed by equations with a minimized number ofparameters therein, it is possible to reduce the number of samplesystems which must be utilized.

In step b. of said procedure the various polarization states can be setutilizing the previously described essentially circular “wheel” elementwith a plurality of discrete polarizer elements mounted thereupon on theperimeter thereof, or can comprise the previously described sliderelement with plurality of discrete polarizer elements mounted thereupon,or using any functionally equivalent means to place the polarizationstate modifier into the pathway of a beam of electromagentic radiation.

It is noted that polarization state modifiers variously cut from, forinstance, low-cost plastic sheets, can be sequentially positioned intothe path of a beam of electromagnetic radiation, via a stepper motor. Itis noted that it is primarily the presence of a plurality of separatesources, or at least one means for transmissively, discretely,sequentially varying polarization states in a beam of polychromaticelectromagnetic radiation in the ellipsometer portion of a presentinvention system, which distinguishes the present invention system overprevious spectroscopic ellipsometer systems which contain continuouslyrotating means for changing polarization states in a beam ofpolychromatic electromagnetic radiation.

Practice can also involve positioning input and outputpolarizer/analyzer system azimuthal angles at typical fixed, nominal,constant plus or minus forty-five (+/−45) degrees, although use ofpolarizer and analyzer elements which are rotatable between dataacquisition procedures is acceptable. It is noted that the staticpositioning of said input and output polarizer/analyzer system azimuthalangles greatly simplifies data acquisition, in that no phase sensors arerequired to detect rotational positioning are necessary, becausesynchronization is unnecessary. That is, as ellipsometric data isacquired asynchronously, the system requirements are greatly reduced ascompared to ellipsometer systems which involve elements that are causedto rotate during data acquisition. Also, as alluded to, fiber optics canbe utilized for transporting electromagnetic radiation to and from theellipsometer system portion of the present invention. The foregoingpoints make it possible to retro-fit mount the ellipsometer portion ofthe present invention to existing spectroscopic reflectometer systems,(such as those presently marketed by Nanometrics Inc.), in a manner thatoptionally involves sharing of a source of electromagnetic radiationand/or detector system thereof with said ellipsometer system.

While the foregoing has disclosed present invention systems, it remainsto describe the mathematical basis for practicing the present invention.As described, the present Discrete Polarization State SpectroscopicEllipsometer (DSP-SE™) system comprises:

-   -   multiple sources which each include transmissive polarization        state setting means to provide different polarization states        when sequentially energized, a stage for supporting a sample        system with a sample system present thereupon, an analyzer, and        a means for detecting beam intensity, (eg. a detector system);        or    -   a source of polychromatic electromagnetic radiation, an optical        element for setting a polarization state, (eg. a polarizer), a        stage for supporting a sample system with a sample system        present thereupon, a means for discretely, sequentially,        modifying a polarization state of a beam of electromagnetic        radiation provided by said source of polychromatic        electromagnetic radiation through a plurality of polarization        states by passage therethrough, an analyzer, and a means for        detecting beam intensity, (eg. a detector system).

As indicated, in practice an input element is typically a polarizer withits transmission axis oriented approximately +45 or −45 degrees from thesample system plane of incidence. Using Mueller Matrix/Stokes VectorCalculus, the input beam passing through such a polarizer is representedby:

$I_{P} = \begin{pmatrix}1 \\{\cos\left( {2P} \right)} \\{\sin\left( {2P} \right)} \\0\end{pmatrix}$where “P” is the azimuthal angle of the polarizer with respect to thesample plane of incidence. For optimal performance over a wide range ofsample systems, and computational simplicity, the “P” is usually chosento be +/−45 degrees, and the Stokes Vector becomes:

$I_{P} = \begin{pmatrix}1 \\0 \\{\pm 1} \\0\end{pmatrix}$

Now, an isotropic sample can be optically modeled by the Mueller Matrix:

$M_{S} = \begin{pmatrix}1 & {- N} & 0 & 0 \\{- N} & 1 & 0 & 0 \\0 & 0 & C & S \\0 & 0 & {- S} & C\end{pmatrix}$and the Stokes Vector resulting from a polarized polychromaticelectromagnetic radiation beam interaction with a sample system isdescribed by:

${M_{S} \cdot I_{P}} = {{\begin{pmatrix}1 & {- N} & 0 & 0 \\{- N} & 1 & 0 & 0 \\0 & 0 & C & S \\0 & 0 & {- S} & C\end{pmatrix} \cdot \begin{pmatrix}1 \\0 \\{\pm 1} \\0\end{pmatrix}} = \begin{pmatrix}1 \\{- N} \\{C \cdot {\pm 1}} \\{{- S} \cdot {\pm 1}}\end{pmatrix}}$

A generalized polarization state modifier (PSM) element, (which cancomprise a combination of elements), followed by a polarization stateinsensitive detector yields the following Stokes Vector:

${PSM} = {{\begin{pmatrix}1 & 0 & 0 & 0\end{pmatrix} \cdot \begin{pmatrix}{m\; 00} & {{m\; 01}\;} & {m\; 02} & {m\; 03} \\{m\; 10} & {m\; 11} & {m\; 12} & {m\; 13} \\{m\; 20} & {m\; 21} & {m\; 22} & {m\; 23} \\{m\; 30} & {m\; 31} & {m\; 32} & {m\; 33}\end{pmatrix}} = \begin{pmatrix}{m\; 00} & {m\; 01} & {m\; 02} & {m\; 03}\end{pmatrix}}$therefore, if there are “n” discrete polarization states, the beamintensity measured for the “n'th” polarization state is:

$I_{n} = {{{PSM}_{n} \cdot M_{S} \cdot I_{P}} = {{\begin{pmatrix}{m\; 0_{n}} & {m\; 1_{n}} & {m\; 2_{n}} & {m\; 3_{m}}\end{pmatrix} \cdot \begin{pmatrix}1 & {- N} & 0 & 0 \\{- N} & 1 & 0 & 0 \\0 & 0 & C & S \\0 & 0 & {- S} & C\end{pmatrix} \cdot \begin{pmatrix}1 \\0 \\{\pm 1} \\0\end{pmatrix}} = {{m\; 0_{n}} - {m\;{1_{n} \cdot N}} + {\left( {{m\;{2_{n} \cdot C}} - {m\;{3_{m} \cdot S}}} \right) \cdot {\pm 1}}}}}$The transfer matrix for traditional 4-detector polarimeter systems isconstructed by inserting the (PSM) into “rows” which correspond to thepolarization state measured by each detector

$I_{n} = {{A \cdot {S\begin{pmatrix}I_{0} \\I_{1} \\I_{2} \\I_{3}\end{pmatrix}}} = {\begin{pmatrix}{m\; 0_{0}} & {{m\; 1_{0}}\;} & {m\; 2_{0}} & {m\; 3_{0}} \\{m\; 0_{1}} & {m\; 1_{1}} & {m\; 2_{1}} & {m\; 3_{1}} \\{m\; 0_{2}} & {m\; 1_{2}} & {m\; 2_{2}} & {m\; 3_{2}} \\{m\; 0_{3}} & {m\; 1_{3}} & {m\; 2_{3}} & {m\; 3_{3}}\end{pmatrix} \cdot \begin{pmatrix}1 \\{- N} \\{C \cdot {\pm 1}} \\{{- S} \cdot {\pm 1}}\end{pmatrix}}}$If the “A” transfer matrix is invertable, (ie. the determinate isnon-zero), it can be concluded that sample system's N, C and Sellipsometric parameters can be determined from the measured intensitiesat each detector.

$\begin{pmatrix}1 \\{- N} \\{C \cdot {\pm 1}} \\{{- S} \cdot {\pm 1}}\end{pmatrix} = {A^{- 1} \cdot \begin{pmatrix}I_{0} \\I_{1} \\I_{2} \\I_{3}\end{pmatrix}}$Furthermore, in a traditional 4-detector polarimeter system, the “A”transfer matrix is determined, (at each wavelength of operation), byinputting a series of known polarization states and measuring theresulting intensities at each detector.

While the present invention (DSP-SE™) is similar to traditional4-detector polarimeter systems, it differs in that more than 4polarization states can optionally be incorporated into the measurement.The “A” matric therefore is generally not “square”, and a simpleinversion can not be used to directly extract sample system N, C and Sellipsometic parameters. Regression analysis based on known opticalmodels can also be used to determine, (ie. calibrate), the “A” transfermatrix of the system, and to extract the ellipsometric parameters fromthe “n” measured intensities.

While many variations are possible, in the preferred, non limiting,embodiment of the present invention the (DSP-SE™) the input polarizer,as mentioned, is fixed at 45 degrees, such that the Stokes Vector whichenters the polarimeter after interaction with the sample system is givenby:

${M_{S} \cdot I_{P}} = {{k \cdot \begin{pmatrix}1 & {- N} & 0 & 0 \\{- N} & 1 & 0 & 0 \\0 & 0 & C & S \\0 & 0 & {- S} & C\end{pmatrix} \cdot \begin{pmatrix}1 \\0 \\1 \\0\end{pmatrix}} = {k \cdot \begin{pmatrix}1 \\{- N} \\C \\{- S}\end{pmatrix}}}$(where “k” is an arbitrary constant which accounts for the unknownintensity provided by the source of polychromatic electromagneticradiation).

For the 1st discrete polarization state of the detector system, apolarizer, (typically termed an analyzer when placed after the samplesystem), with the azimuthal angle thereof set at 45 degrees, thedetected intensity is of the form:

$I_{0} = {{{PSM}_{0} \cdot M_{S} \cdot I_{P}} = {{\begin{pmatrix}1 & 0 & {- 1} & 0\end{pmatrix} \cdot k \cdot \begin{pmatrix}1 \\{- N} \\C \\{- S}\end{pmatrix}} = {k \cdot \left( {1 - C} \right)}}}$For the next two discrete polarization states, a quarter-wave retardercan be inserted in front of the analyzer, at azimuthal angles of zero(0.0) and ninety (90) degrees respectively, to provide:

$I_{1} = {{{PSM}_{1} \cdot M_{S} \cdot I_{P}} = {{\begin{pmatrix}1 & 0 & {- 1} & 0\end{pmatrix} \cdot \begin{pmatrix}1 & 0 & 0 & 0 \\0 & 1 & 0 & 0 \\0 & 0 & 0 & 1 \\0 & 0 & {- 1} & 0\end{pmatrix} \cdot k \cdot \begin{pmatrix}1 \\{- N} \\C \\{- S}\end{pmatrix}} = {k \cdot \left( {1 + S} \right)}}}$  (for  retarder  @  0^(∘))$I_{2} = {{{PSM}_{2} \cdot M_{S} \cdot I_{P}} = {{\begin{pmatrix}1 & 0 & {- 1} & 0\end{pmatrix} \cdot \begin{pmatrix}1 & 0 & 0 & 0 \\0 & 1 & 0 & 0 \\0 & 0 & 0 & {- 1} \\0 & 0 & 1 & 0\end{pmatrix} \cdot k \cdot \begin{pmatrix}1 \\{- N} \\C \\{- S}\end{pmatrix}} = {k \cdot \left( {1 - S} \right)}}}$  (for  retarder  @  90^(∘))For two additional discrete polarization states, a quarter-wave retardercan be inserted in front of the analyzer, at azimuthal angles of+/−twenty-two (22) degrees, respectively, to provide:

$I_{3} = {{{PSM}_{3} \cdot M_{S} \cdot I_{P}} = {{\begin{pmatrix}1 & 0 & {- 1} & 0\end{pmatrix} \cdot \begin{pmatrix}1 & 0 & 0 & 0 \\0 & \frac{1}{2} & \frac{1}{2} & {\frac{- 1}{2} \cdot \sqrt{2}} \\0 & \frac{1}{2} & \frac{1}{2} & {\frac{1}{2} \cdot \sqrt{2}} \\0 & {\frac{1}{2} \cdot \sqrt{2}} & {\frac{- 1}{2} \cdot \sqrt{2}} & 0\end{pmatrix} \cdot k \cdot \begin{pmatrix}1 \\{- N} \\C \\{- S}\end{pmatrix}} = {\left( {1 - {\frac{1}{2} \cdot C} + {\frac{1}{2} \cdot N} + {\frac{1}{2} \cdot \sqrt{2} \cdot S}} \right) \cdot {k\mspace{20mu}\left( {{for}\mspace{14mu}{{retarder}\mspace{14mu}@\mspace{14mu}{+ 22.5}}{^\circ}} \right)}}}}$$I_{2} = {{{PSM}_{4} \cdot M_{S} \cdot I_{P}} = {{\begin{pmatrix}1 & 0 & {- 1} & 0\end{pmatrix} \cdot \begin{pmatrix}1 & 0 & 0 & 0 \\0 & \frac{1}{2} & \frac{- 1}{2} & {\frac{1}{2} \cdot \sqrt{2}} \\0 & \frac{- 1}{2} & \frac{1}{2} & {\frac{1}{2} \cdot \sqrt{2}} \\0 & {\frac{- 1}{2} \cdot \sqrt{2}} & {\frac{- 1}{2} \cdot \sqrt{2}} & 0\end{pmatrix} \cdot k \cdot \begin{pmatrix}1 \\{- N} \\C \\{- S}\end{pmatrix}} = {\left( {1 + {\frac{1}{2} \cdot \sqrt{2} \cdot S} - {\frac{1}{2} \cdot N} - {\frac{1}{2} \cdot C}} \right) \cdot {k\mspace{20mu}\left( {{for}\mspace{14mu}{{retarder}\mspace{14mu}@\mspace{14mu}{- 22.5}}{^\circ}} \right)}}}}$Simple combinations of these intensities yield:1₀ =k·(1−C) 1₁−1₂=2·k·S 1₁+1₂=2·k 1₃−1₄ =k·Nfrom which sample system N, C, S, and are easily derived as:

${N = {{{2 \cdot \frac{I_{3} - I_{4}}{I_{1} + I_{2}}}\mspace{31mu} C} = {{\frac{\left( {I_{1} + I_{2} - {2 \cdot I_{0}}} \right)}{\left( {I_{1} + I_{2}} \right)}\mspace{31mu} S} = \frac{\left( {I_{1} - I_{2}} \right)}{\left( {I_{1} + I_{2}} \right)}}}}\;$$\Delta = {{a\;{\tan\left( \frac{S}{C} \right)}\mspace{31mu}\Psi} = {{\frac{1}{2} \cdot a}\;{\tan\left( \frac{\sqrt{C^{2} + S^{2}}}{N} \right)}}}$While the math for the preceeding 5-state (DSP-SE™) system is elegant, apotential difficulty in implementing said design is that insertion ofthe quarter-wave plates to effect polarization states 1-4, introducesintensity loss as a result of reflection from the optical elementsurface, which is not present when obtaining the first data set whereinno quarter-wave plate is present. This additional intensity loss must beaccounted for in the calibration algorithm. A modified approach involvesnot obtaining or not utilizing the first data set. While this slightlycomplicates the equations, a simple analytic solution is still possibleand values for N, C and S can be derrived as:1₁−1₂=2·k·S 1₁+1₂=2·k 1₃−1₄ =k·N 1₃+1₄=(2−C+√{square root over (2)}·S)·k

$N = {{{2 \cdot \frac{\left( {I_{3} - I_{1}} \right)}{\left( {I_{1} + I_{2}} \right)}}\mspace{31mu} C} = \frac{{\left( {2 - \sqrt{2}} \right) \cdot I_{2}} + {\left( {2 + \sqrt{2}} \right) \cdot I_{1}} - {2 \cdot \left( {I_{3} + I_{4}} \right)}}{\left( {I_{1} + I_{2}} \right)}}$$S = \frac{\left( {I_{1} - I_{2}} \right)}{\left( {I_{1} + I_{2}} \right)}$A more general 4-state (DSP-SE™) approach utilizes an input polarizer,an output analyzer and four (4) retarder elements at various azimuthalorientations. In this approach, while the azimuthal orientations for theoptical elements are nominally chosen to be the same as in thepreceeding design, arbitrary azimuthal orientations as well asnon-ninety degree retardation values are allowed. Under this approach,the Stokes Vector provided to the Polarimeter is given by:

$\begin{matrix}{I_{S,P} = {{\begin{pmatrix}1 & {- N} & 0 & 0 \\{- N} & 1 & 0 & 0 \\0 & 0 & C & S \\0 & 0 & {- S} & C\end{pmatrix} \cdot \begin{pmatrix}1 \\{\cos\left( {2P} \right)} \\{\sin\left( {2P} \right)} \\0\end{pmatrix}} = {\begin{pmatrix}{1 - {N \cdot {\cos\left( {2 \cdot P} \right)}}} \\{{- N} + {\cos\left( {2 \cdot P} \right)}} \\{C \cdot {\sin\left( {2 \cdot P} \right)}} \\{{- S} \cdot {\sin\left( {2 \cdot P} \right)}}\end{pmatrix} = \begin{pmatrix}{s\; 0} \\{s\; 1} \\{s\; 2} \\{s\; 3}\end{pmatrix}}}} & \left( {{DPS}\mspace{14mu}{\# 1}} \right)\end{matrix}$(where “P” is the input polarimeter azimuth).The response of each discrete polarization state “n” to an input StokesVector is:

$\begin{matrix}\begin{matrix}{1_{n} = \left( {m\; 0_{n}\mspace{14mu} m\; 1_{n}\mspace{14mu} m\; 2_{n}\mspace{14mu} m\; 3_{n}} \right)} & {{m\; 0_{n}} = 1} \\\; & {{m\; 1_{n}} = {{{\left( {{{cr}_{n} \cdot {sr}_{n}} - {c\;{\delta_{n} \cdot {sr}_{n} \cdot {cr}_{n}}}} \right) \cdot S}\; 2A} + \left( {cr}_{n} \right)^{2} + {c\;{\delta_{n} \cdot \left( {sr}_{n} \right)^{2} \cdot C}\; 2A}}} \\\; & {{m\; 2_{n}} = {{{\left\lbrack {\left( {sr}_{n} \right)^{2} + {c\;{\delta_{n} \cdot \left( {cr}_{n} \right)^{2}}}} \right\rbrack \cdot S}\; 2A} + {{\left( {{{sr}_{n} \cdot {cr}_{n}} - {c\;{\delta_{n} \cdot {cr}_{n} \cdot {sr}_{n}}}} \right) \cdot C}\; 2A}}} \\\; & {{m\; 3_{n}} = {{\left( {{S\; 2{A \cdot {cr}}} - {C\; 2{A \cdot {sr}}}} \right) \cdot s}\;\delta}}\end{matrix} & \left( {{DPS}\mspace{14mu}{\# 2}} \right)\end{matrix}$wherecr=cos(2r), sr=sin(2r)·cδ=cos(δ)·sδ=sin(δ)·C2A=cos(2A)··S2A=sin(2A)·r isthe retarder azimuthal orientation angle, δ is the retardance, and A isthe analyzer orientation.

-   -   (for most retarders, the retardance varies inversely with        wavelength, that is δ(λ)=δ_(c)/λ)        These polarization state modifying vectors can be packed into a        (4×4) square transfer matrix “A”, such that the measured        intensity for each discrete state is given by:

$I_{n} = {{A \cdot {I_{S,P}\begin{pmatrix}I_{0} \\I_{1} \\I_{2} \\I_{3}\end{pmatrix}}} = {\begin{pmatrix}{m\; 0_{0}} & {m\; 1_{0}} & {m\; 2_{0}} & {m\; 3_{0}} \\{m\; 0_{1}} & {m\; 1_{1}} & {m\; 2_{1}} & {m\; 3_{1}} \\{m\; 0_{2}} & {m\; 1_{2}} & {m\; 2_{2}} & {m\; 3_{2}} \\{m\; 0_{3}} & {m\; 1_{3}} & {m\; 2_{3}} & {m\; 3_{3}}\end{pmatrix} \cdot \begin{pmatrix}{s\; 0} \\{s\; 1} \\{s\; 2} \\{s\; 3}\end{pmatrix}}}$To determine the Stokes Vector incident on the Polarimeter, the transfermatrix “A” s inverted and multiplied times the measured intensitiescorresponding to each discrete polarization state:

$\begin{pmatrix}{s\; 0} \\{s\; 1} \\{s\; 2} \\{s\; 3}\end{pmatrix} = {\begin{pmatrix}{m\; 0_{0}} & {m\; 1_{0}} & {m\; 2_{0}} & {m\; 3_{0}} \\{m\; 0_{1}} & {m\; 1_{1}} & {m\; 2_{1}} & {m\; 3_{1}} \\{m\; 0_{2}} & {m\; 1_{2}} & {m\; 2_{2}} & {m\; 3_{2}} \\{m\; 0_{3}} & {m\; 1_{3}} & {m\; 2_{3}} & {m\; 3_{3}}\end{pmatrix}^{- 1} \cdot \begin{pmatrix}I_{0} \\I_{1} \\I_{2} \\I_{3}\end{pmatrix}}$and the sample system parameters:

$N = {{{\cos\left( {2 \cdot P} \right)} - {s\; 1\mspace{31mu} C}} = {{\frac{s\; 2}{\sin\left( {2 \cdot P} \right)}\mspace{31mu} S} = \frac{{- s}\; 3}{\sin\left( {2 \cdot P} \right)}}}$can then be extracted. To illustrate this approach, a transfer matrix isconstructed assuming nominal azimuthal orientations of (0.0), (90)(+22.5) and (−22.5) degrees for each of the four (4) discretepolarization states. The same nominal retardance is assumed for eachretarder. The analytical inversion of this matrix is very complicated,but it is still trivial to numerically invert the matrix given thesample expressions for each element given by:

$A = \begin{bmatrix}1 & {C\; 2A} & {c\;{\delta \cdot S}\; 2A} & {S\; 2{A \cdot s}\;\delta} \\1 & {C\; 2A} & {c\;{\delta \cdot S}\; 2A} & {- \left( {S\; 2{A \cdot s}\;\delta} \right)} \\1 & {{\left( {1 - {c\;\delta}} \right) \cdot \frac{S\; 2A}{2}} + {\left( {1 + {c\;\delta}} \right) \cdot \frac{C\; 2A}{2}}} & {{\left( {1 + {c\;\delta}} \right) \cdot \frac{S\; 2A}{2}} + {\left( {1 - {c\;\delta}} \right) \cdot \frac{C\; 2A}{2}}} & {{\left( {{S\; 2A} - {C\; 2A}} \right) \cdot s}\;{\delta \cdot \frac{\sqrt{2}}{2}}} \\1 & {{{- \left( {1 - {c\;\delta}} \right)} \cdot \frac{S\; 2A}{2}} + {\left( {1 + {c\;\delta}} \right) \cdot \frac{C\; 2A}{2}}} & {{\left( {1 + {c\;\delta}} \right) \cdot \frac{S\; 2A}{2}} - {\left( {1 - {c\;\delta}} \right) \cdot \frac{C\; 2A}{2}}} & {{\left( {{S\; 2A} + {C\; 2A}} \right) \cdot s}\;{\delta \cdot \frac{\sqrt{2}}{2}}}\end{bmatrix}$Multiplying the inverted matrix by the measured intensities for eachdiscrete polarization state allows straight forward determination of thesample system characterizing N, C, S, ψ, and Δ.A General Regression Based Approach to Calibration of (DSP-SE™) systemsand allow extraction of accurate ellipsometric sample systemcharacterizing data assumes that the (DSP-SE™) system measurespolychromatic electromagnetic radiation beam intensity at “n” discretepolarization states, and that “m” samples with different ellipsometricproperties are utilized. For a traditional polarimeter system, which iscalibrated on a wavelength by wavelength basis, it is necessary to have“m” be greater than or equal to “n”. However, utilizing globalregression which allows calibration parameters to be parameterized vs.wavelength, (thereby reducing the number of parameters required todescribe the system transfer Matrices “A” at each wavelength), it ispossible to reduce the number of calibration sample systems required,“m”, to be less than “n”. Under this approach, calibration of a presentinvention (DSP-SE™) system, a multi-dimensional data set “I” is measuredconsisting of measured polychromatic electromagnetic radiation beamintensities for each discrete polarization state, on each calibrationsample system, and at each wavelength in the spectral range of theinstrument:

${{igen}\left( p_{y} \right)}_{i,j,k} = {A \cdot \begin{pmatrix}1 & {- N_{j,k}} & 0 & 0 \\{- N_{j,k}} & 1 & 0 & 0 \\0 & 0 & C_{j,k} & S_{j,k} \\0 & 0 & {- S_{j,k}} & C_{j,k}\end{pmatrix} \cdot \begin{pmatrix}s_{0} \\s_{1} \\s_{2} \\s_{3}\end{pmatrix}}$To generate “predicted” intensities measured by the (DSP-SE™), (as afunction of calibration parameters spsecified in the vector p_(y)), thefollowing equation is applied:Iexp_(i,j,k)

-   -   where        -   i=1 . . . n (for each discrete polarization state)        -   j=1 . . . m (for each calibration sample)        -   k=1 . . . w (for each wavelength)            where “A” is an (“n”×4) matrix, in which each row is            possibly parameterized by foregoing equation DSP#2 and the            input vector s is possibly parameterized by the input            polarizer azimuth by an equation DSP#1. The extraction of            calibration sample system's N, C and S parametres can be            calculated as a function of film thickness and angle of            incidence (given calibration sample systems which are well            characterized by known optical models and optical constants,            such as SiO₂ on Si films with systematically increasing SiO₂            film thicknesses).

To perform regression analysis, the “chi-squared” function:

$\chi^{2} = {\sum\limits_{i = 1}^{n}{\sum\limits_{j = 1}^{m}{\sum\limits_{k = 1}^{w}\left\lbrack {\frac{I\;\exp_{i,j,k}}{\sqrt{\sum\limits_{i = 1}^{m}\left( {I\;\exp_{i,j,k}} \right)^{2}}} - \frac{I\;{{gen}\left( p_{y} \right)}_{i,j,k}}{\sqrt{\sum\limits_{i = 1}^{m}\left( {I\;{{gen}\left( p_{y} \right)}_{i,j,k}} \right)^{2}}}} \right\rbrack^{2}}}}$is then minimized, (typically utilizing a non-linear regressionalgorithm such as “Marquard-Levenberg”), by adjusting calibrationparameters specified in the vector “p_(y)”. To aid in the regression,both the experimental and generated intensity vectors are normalized bythe sum of the squares of all the discrete polarization states at eachwavelength.

If the global parameterization of calibration parameters is not used,then the vector “p_(y)” consists of the input Stokes Vector values“s_(n)”, and the elements of the transfer matrix “A”, all of which mustbe defined at each wavelength, This requires at least (4+(4×n))×w)calibration parameters, assuming that the ellipsometric parameters (N, Cand S), for each calibration sample system are exactly known.

Further, if global parameterization is used, the input vector “s_(n)”for all wavelengths can be parameterized by the input polarizer azimuth“P”, the ellipsometric parameters of the “m” calibration samples can beparametrically calculated as a function of angle of incidence (θ) andfilm thickness “t_(m)”, and the transfer matrix “A” can be parameterizedby the Azimuth of the analyzer “A”, the orientation of each retarder“r_(n)”, and the retardance of each retarder as a function of wavelengthδ(λ)_(n)=δc_(n)/λ. It is noted that higher order terms could also beadded to the retardance vs. wavelength function, or to any other of thecalibration parameters to improve fit between the experimentallymeasured and modeled generated data. Such a global parameterizationsignificantly reduces the number of calibration parameters required todescribe the (DSP-SE™) system over a spectroscopic range of wavelengths.The total number of calibration parameters in this suggestedparameterization (other variations are certainly possible as well), maybe as few as:p _(y) =P+φ _(m) +t _(m) +A+r _(n) +δc _(m)=1+m+m+1+n+m=(2×m)+(2×n)+2.To extract the ellipsometric parameters of an arbitrary sample systemwhich is inserted into a general (DSP-SE™) system, a regression analysiscan also be performed, and N, C and S can be defined and evaluated byregression at each wavelength separately.

Further, if the plane of incidence of the sample system is allowed tovary slightly, (to account for imperfect alignment to the ellipsometersystem), the Stokes Vector which enters the discrete polarization statemodifier becomes:

${M_{S} \cdot I_{P}} = {{k \cdot \begin{pmatrix}1 & 0 & 0 & 0 \\0 & {\cos(s)} & {- {\sin(s)}} & 0 \\0 & {\sin(s)} & {\cos(s)} & 0 \\0 & 0 & 0 & 1\end{pmatrix} \cdot \begin{pmatrix}1 & {- N} & 0 & 0 \\{- N} & 1 & 0 & 0 \\0 & 0 & C & S \\0 & 0 & {- S} & C\end{pmatrix} \cdot \begin{pmatrix}1 & 0 & 0 & 0 \\0 & {\cos(s)} & {\sin(s)} & 0 \\0 & {- {\sin(s)}} & {\cos(s)} & 0 \\0 & 0 & 0 & 1\end{pmatrix} \cdot \begin{pmatrix}1 \\0 \\1 \\0\end{pmatrix}} = {k \cdot \begin{bmatrix}{1 - {s \cdot N}} \\{{- N} + {s \cdot \left( {1 - C} \right)}} \\{{{- s} \cdot N} + C} \\{- S}\end{bmatrix}}}$where “s” is the azimuthal misalignment of the sample system, andpresumably is very near zero.In this case the (DSP-SE™) system, would not measure the “true” N, C andS parameters, but would instead measure “effective” parameters Neff,Ceff and Seff:Neff=N−s·(1−C) Ceff=C−s·N Seff=SIt would be possible to include the azimuthal misalignment factor “s” asa fitting parameter in subsequent analysis of the ellipsometric datameasured by a (DSP-SE™) system.

It is believed that the present invention spectroscopic ellipsometersystem combination comprising:

-   -   no moving elements during data acquisition; and    -   means for discretely, sequentially, providing a beam of        electromagnetic radiation which is sequenced through plurality        of polarization states, said means being a plurality of sources        which are sequentially energized, or means present at least one        location selected from the group consisting of:        -   between said polarizer and said stage for supporting a            sample system; and        -   between said stage for supporting a sample system and said            analyzer;            said at least one means discretely, sequentially providing a            beam of electromagnetic radiation which demonstrates a            plurality of non-continuously changing polarization states;            is Patentably distinct over all prior art.            Patentability is thought to be further enhanced when (LED's)            are utilized, and where the source of polychromatic            radiation comprises a system for providing an output beam of            polychromatic electromagnetic radiation, which has a            relatively broad and flattened intensity vs. wavelength            characteristic over a wavelength spectrum. Said result can            be achieved by application Of a system which comprises at            least a first and a second source of polychromatic            electromagnetic radiation; and at least a first            electromagnetic beam combining means comprising a plate,            (eg. uncoated fused silica or glass etc. such that            reflection/transmission characteristics thereof are            determined by angle-of-incidence and polarization state of a            beam of electromagnetic radiation). A similar relatively            broad and flattened intensity vs. wavelength characteristic            result can be achieved by application of a Beam Chromatic            Shifting and Directing Means (ZCM) which comprises a Silicon            Substrate (SI) upon the surface of which is present between            about 500 and 1500 Angstroms, (nominal 600 or 1200            Angstroms), of Silicon Dioxide (SIO2).

It is also noted that while better presented in Co-Pending applicationSer. No. 09/945,962 from which this application is a CIP, SequentialDiscrete Polarization States can be set by at least one RotatableCompensator, preferably as mounted in a hollow shaft suitable forcontrol by a stepper motor. Such a configuration is known for Polarizersand Analyzers, but is not known for Compensators.

Also, it is noted that detection can be emphasized in ElectromagneticSpectrum IR and UV wavelengths by reflecting a beam substantiallycentered in the Visual, off such as a Silicon Substrate with, forexample 500-1500 Angstroms of SiO2 present on the surface thereof.Suitable Detectors can include a Grating/Prism and a Diode Array, or asingle detector for spectroscopic and monchromatic wavelengths,respectively.

It is also noted that selection of discrete polarization states can bemade on the basis of the characteristics of a Sample, such that Sampleproperties can be better evaluated.

The present invention will be better understood by reference to theDetailed Description Section of this Specification, in combination withthe Drawings.

SUMMARY

It is therefore a primary purpose and/or objective of the presentinvention to disclose a low cost spectroscopic ellipsometer system whichcomprises a plurality of discrete, separately energizable sources ofelectromagnetic radiation, each of which has associated therewith aseparate means for setting a polarization state onto the beam ofelectromagnetic radiation provided by one of said sources.

It is yet another purpose and/or objective of the present invention todisclose use of a beam splitting analyzer in said low cost spectroscopicellipsometer system which, in use, has no moving parts.

It is another purpose and/or objective yet of the present invention todisclose preferred, but not limiting, sources of electromagneticradiation as being light emitting diodes, in particular wide band whitelight emitting diodes.

It is another purpose and/or objective of the present invention todisclose methodology of application of said low cost spectroscopicellipsometer system in which the source of a plurality of polarizationstates has no moving parts during data collection.

It is another purpose and/or objective of the present invention todisclose use of a beam combining means for combining multiple beams ofelectromagnetic radiation to form a more uniform intensity vs.wavelength source, in a low cost spectroscopic ellipsometer system.

Other purposes and/or objectives will become clear from a reading of theSpecification and Claims.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 a shows a typical spectroscopic ellipsometer systemconfiguration.

FIG. 1 b shows a preferred disclosed invention spectroscopicellipsometer system configuration.

FIG. 1 c shows a Detector suitable for use with the FIG. 1 bspectroscopic ellipsometer system.

FIGS. 2 a-2 d show a combined spectroscopic reflectometer/ellipsometersystem which can utilize the FIG. 1 b source of electromagneticradiation.

FIG. 3 a shows a frontal perspective view of a discrete state polarizercomprising a wheel with five discrete polarizer elements mountedthereupon.

FIG. 3 b shows a side elevational view of a discrete state polarizer, asin FIG. 3 a, oriented so that an electromagnetic beam passing throughone of the discrete polarizer five elements.

FIG. 3 c shows a front elevational view of a discrete state polarizerwith five laterally slideably mounted discrete polarizer elementsmounted therein.

FIG. 3 d 1 shows a system for providing an output beam (OB) or (OB′) ofpolychromatic electromagnetic radiation which has a relatively broad andflattened intensity vs. wavelength characteristic over a wavelengthspectrum.

FIGS. 3 d 2 and 3 d 3 show an alternative system for emphasizing IR andUV wavelength Spectrum Intensity.

FIG. 4 a demonstrate flow of use of the present invention.

FIG. 4 b demonstrates the flow of a present invention method ofcalibration of the present invention spectroscopic ellipsometer.

FIGS. 5-11 show Intensity vs. Wavelength for the seven (7)ellipsometrically different samples, obtained by fitting a mathematicalmodel of the samples and a spectroscopic ellipsometer system byregression onto experimentally obtained data obtained at each of five(5) discrete polarization states.

FIGS. 12 & 13 show PSI and DELTA values obtained for samples with thinand thick layers of Oxide thereupon utilizing discrete, rather thancontinuously varying polarization state data.

DETAILED DESCRIPTION

Turning now to FIG. 1 a, there is shown a representation of a typicalspectroscopic ellipsometer system configuration. Shown are a source ofpolychromatic electromagnetic radiation (QTH), (eg. a quartztungsten-halogen-lamp), a polarizer (P), an optional Compensator (C), astage for supporting a sample system (STG) with a sample system (SS)present thereupon, an optional Compensator (C), an analyzer (A), and adetector system (DET). Note detector systems can be spectroscopicmulti-element such as Bucket Brigade, Diode and CCD arrays and that“off-the-shelf” spectrometer systems such as manufactured by Zeiss canalso be applied). Shown also are ellipsometer electromagnetic beam in(EBI) and ellipsometer electromagnetic beam out (EBO). Further are shownFocusing and Collimating Lenses (FE) (FE′), which are preferablyachromatic. In use at least one of the Polarizer and/or Analyzer and/orCompensator is caused to rotate during data acquisition.

In contrast to the system shown in FIG. 1 a, FIG. 1 b shows a preferredpresently disclosed low complexity spectroscopic ellipsometer systemconfiguration, which in use during data acquisition has no moving parts.Shown are Sources of electromagnetic radiation (S1), (S2), (S3) and(S4), each having an associated Polarizer Means (P1), (P2), (P3) and(P4), respectively, associated therewith. (For instance, thePolarization States imposed by (P1), (P2), (P3) and (P4) can be selectedto be −45, 0.0, +45 and 90 Degrees respectively). Also shown are BeamCombining means (BC1) and (BC2). Note that Beam Combining Means (BC1)serves to combine Beams of electromagnetic Radiation (B1) and (B2) fromSources (S1) and (S2) respectively, and produce Beam (B5). Note thatSources (S1) and (S2) have Polarization Means (P3) and (P4) associatedtherewith. Continuing, Beam (B5) enters Beam Combiner Means (BC2), whichalso receives Beam (B6), said Beam (B6) being a combination of beams(B3) and (B4) which exits Beam Combiner (BC3). Beam (B7) exits BeamCombiner (BC2) and passes through Lens (L1) before impinging onto theSample. The pathways from each sources of electromagnetic radiation(S1), (S2), (S3) and (S4) should be noted are preferably selected to besubstantially equal to the point of interacting with the Sample. (Notethat elements (S1), (S2), (S3) and (S4); (P1), (P2), (P3) and (P4),(BC1), (BC2) and (BC3) and (L1) in combination are sometimes referred toas a Polarization State Generator (PSG)). Reflected Beam (B7′) is shownentering a Detector (DET) via a functionally combined Analyzer (A1) andRotation Stage (R1). (The rotation stage allows for setting multipleAnalyzer (A) azimuthal settings during system calibration). Also shownis a Lens (L2) which focuses electromagnetic radiation onto the Detector(DET). (For instance, in use where (P1), (P2), (P3) and (P4) can beselected to be −45, 0.0, +45 and 90 Degrees respectively, (R1) might beset to orient the azimuth of (A1) at +45 degrees). (Note that saidelements (A1), (R1) (L2) and (DET) are sometimes referred to as aPolarization State Detector (PSD)).

FIG. 1 c better shows a Polarization State Detector (PSD) which issuitable for use with the FIG. 1 b spectroscopic ellipsometer system. Itcomprises a functionally combined Rotation Stage (R2) and a BeamSplitting Analyzer (A2), which Beam Splitting Analyzer (A2) outputs twoPolarization State Dependent Beams, (S8) AND (B9), which are interceptedby Detectors (D1) and (D2), respectively.

As described in the Disclosure of the Invention Section, in use thevarious Sources (S1), (S2), (S3) and (S4) are sequentially energized tosequentially provide Beam (B7), which has a progression of polarizationstates dependent on which Source was energized. It should be apparentthat with no moving parts required, a sequence of polarization statescan then be sequentially presented to the Sample. This is considered avery important aspect of the preferred embodiment of the disclosedinvention.

In the disclosed invention, multiple light sources are applied togenerate different polarization states which are utilized incharacterizing a Sample. While conventional ellipsometer Sources, (eg.Lasers and Arc Lamps), are expensive, Light Emitting Diodes, (LED's) arereadily available and inexpensive, (typically less than $5.00 each). Inaddition, (LED's) are Solid Statem, have no moving parts, generate verylittle heat, are highly efficient and have very long lifetimes (eg.greater than 100,000 hours). Further, as alluded to, (LED's) can bemodulated, (ie. turned on and off). While discrete wavelength (LED's)have been available for years, it is only relatively recently that white(LED's), which produce wavelengths throughout the Visible Range, havebecome available. While not productive of as intense an output asconventional Sources, and not allowing for as high a degree ofcollimation, the compact design of spectroscopic ellipsometers enabledby their use facilitates realization of ellipsometer systems withdivergence minimizing short beam pathlengths therefrom to a sample.

It is also noted that use of colored output (LED's) results in ovenlower costs than does use of White (LED's). And, where Colored (LED's)are utilized, a system as shown in FIG. 3 d 1 can be used to combine theoutputs from a plurality thereof at, at least some of the (S1), (S2),(S3) and (S4) Source locations, (see discussion of FIG. 3 d below).Where Colored (LED's) are used, Silicon Photodetectors, instead of moreexpensive CCD Detectors, can be utilized as the Detector (DET). Andsince the wavelengths developed are known, said Silicon Photodetectorscan be chosen for optimum sensitivity.

FIGS. 1 b and 1 c show the preferred embodiment of the disclosedinvention. In the following, other systems which can be utilized as lowcost ellipsometers, but which require moving parts are described.

FIGS. 2 a-2 d show a combined spectroscopic reflectometer/ellipsometersystem wherein the source of polychromatic electromagnetic radiation(QTH), and detector (DET) system are common to both, and wherein thespectroscopic ellipsometer system is shown as being provided input andoutput electromagnetic beam access via fiber optics (F1) and (F2). Shownare near-normal orientation reflectometer electromagnetic beam in (RBI)and reflectometer electromagnetic beam out (RBO), as well as samplesystem (SS) specific near Brewster condition ellipsometerelectromagnetic beam in (EBI) and ellipsometer electromagnetic beam out(EBO). While not shown, it is noted that the source of polychromaticelectromagnetic radiation (QTH), and detector (DET) system can belocated distal from both the reflectometer and ellipsometer portions ofthe combined spectroscopic reflectometer/ellipsometer system, with fiberoptics being present to interface to the reflectometer portion as well.

In both FIGS. 1 a and 2 a-2 d, there can optionally be other (eg.focusing elements ((FE′) (FE′)), present on one or both sides of thesample system (SS), as shown in dashed lines. Said other elements appearellipsometrically indistinguishable with polarization state modifiers,(ie. (A), (B), (C) etc.) during use.

FIG. 2 a shows a combined spectroscopic reflectometer/ellipsometermetrology system wherein the source of polychromatic electromagneticradiation (QTH), and detector (DET) system are common to both, andwherein the spectroscopic ellipsometer system is shown as being providedinput and output electromagnetic beam access via fiber optics (F1) and(F2). Shown are near-normal orientation reflectometer electromagneticbeam in (RBI) and reflectometer electromagnetic beam out (RBO), as wellas sample system (SS) specific near Brewster condition ellipsometerelectromagnetic beam in (EBI) and ellipsometer electromagnetic beam out(EBO). While not shown, it is noted that the source of polychromaticelectromagnetic radiation (QTH), and detector (DET) system can belocated distal from both the reflectometer and ellipsometer portions ofthe combined spectroscopic reflectometer/ellipsometer metrology system,with fiber optics being present to interface to the reflectometerportion as well.

In both FIGS. 1 a and 2 a, there can optionally be other (eg. focusingelements ((FE′) (FE′)), present on one or both sides of the samplesystem (SS), as shown in dashed lines. Said other elements appearellipsometrically indistinguishable with polarization state modifiers,(ie. (A), (B), (C) etc.) during use.

FIGS. 2 b-2 d show various embodiments of combined present inventionspectroscopic reflectometer/ellipsometer systems, described as metrologysystems.

Considering first FIG. 2 b, there is shown therein a metrology system(150) in which a source of electromagnetic radiation (152) provides twobeams of electromagnetic radiation (152 a) and (152 b). Beam (152 b)interacts with optical elements (174), (172), (175), (176) and (178)before reflecting from sample (108). Reflected electromagnetic beam (152b) passes through optical elements (180) and (184), reflects from mirror(186), passes through lens (188), and is focused into entrance slit(166) of detector system (154), by beam splitter (162). Electromagneticbeam (152 a) passes through optical elements (154), (156), (158), (160)and (161), then reflects from beam splitter (162) into sample (108) vialens 164, with the beam reflected from the sample (108) then beingdirected via lens (164) through beam splitter (162) into the detector(154) through entrance slit (166).

FIG. 2 c shows that metrology system (250), (which is analogicallysimilar to metrology system 150 shown in FIG. 2 b), having a singlelight source (152) and a single light detector (154). A single beam ofelectromagnetic radiation (253) is produced by said light source (152)and is split into reflectometer (253 a) and an ellipsometer (253 b)beams of electromagnetic radiation by beam splitter (256). A series ofoptics, shown as a single lens (258) for the sake of simplicity, is usedto direct light beam (253 a) to beam splitter (162) and focus beam (253a) on sample (108) via lens (164). The ellipsometer beam (253 b) isredirected with mirror (264) towards the ellipsometric optical elements(174), (175), (176) and (178). Electromagnetic radiation reflected offsample (108) passes through another series of ellipsometric elements(180) (182) and (184) and is entered to fiber optics (270) via lens(271). Electromagnetic radiation (exiting said fiber optics (270) isfocused via lens (272) onto beam splitter (162) and directed throughentrance slit (166) into detector (254). The fiber optics, it is noted,eliminates the need for electromagnetic beam redirecting means afterreflection from the sample (108) and prior to beam splitter (162), thusenabling overall metrology system size reduction.

Focusing now on FIG. 2 d, there is shown another embodiment of a presentinvention metrology system (300), (which is similar to metrology system(150) shown in FIG. 2 b). Single electromagnetic beam (303) is producedby source (152) and is split into beams (303 a) and (303 b) by beamsplitter (162). The reflectometer optical path for electromagnetic beam(303 a) is similar to that described for the reflectometerelectromagnetic beam described in FIG. 2 c, but ellipsometerelectromagnetic beam (303 b) is caused to reflect from mirror (304) andbecome directed onto sample (108) via optical elements (174), (175),(176) and (178). The electromagnetic beam (303 b) which reflects fromsample (108) passes through optical elements (180), (182) & (184) andenters fiber optics (310) via lens (271). The electromagnetic beamexiting the fiber optics (310) is, via lens (312), then focused ontoentrance slit (166) of detector (254) by beam splitter (314).

With respect to the presently disclosed invention of FIG. 1 b, note thatthe Source (152) can be the Polarization State Generator of FIG. 1 b,including the beam combining system of FIG. 3 d 1.

It should be appreciated that FIGS. 2 b-2 d show exemplary and notlimiting embodiments of combined spectroscopicreflectometer/ellipsometer metrology systems.

FIG. 3 a shows a frontal perspective view of a discrete state polarizer(DSP) comprising an essentially circular “wheel” element (WE) with fivediscrete polarization state modifiers elements (A) (B) (C) (D) and (E)mounted thereupon on the perimeter thereof, such that said andprojecting discrete polarization state modifier elements (A) (B) (C) (D)and (E) project perpendicularly to a surface thereof.

FIG. 3 b shows a side elevational view of a discrete state polarizer, asin FIG. 3 a, oriented so that an electromagnetic beam (EM) passingthrough one (C) of the five discrete polarization state modifiers (A)(B) (C) (D) and (E) elements. Note that discrete polarizer elements (A)and (B) are located behind discrete polarizer elements (E) and (D)respectively. Also note that if the essentially circular “wheel” element(WE) is caused to rotate about the pivot rod (PR) which projects from alower surface of said essentially circular “wheel” element, each of thevarious five discrete polarizer (A) (B) (C) (D) and (E) elements can berotated into the position in which is shown discrete polarizer element(C).

FIG. 3 c shows a front elevational view of a discrete state polarizerwith five laterally slideably mounted discrete polarizer (A) (B) (C) (D)and (E) elements mounted on a slider element (SE) which is mounted in aguide providing element (GE) therein. Sliding the slider element (SE) tothe right or left serves to position each of the five discrete polarizer(A) (B) (C) (D) and (E) elements in a position at which anelectromagnetic beam of radiation can be caused to be present.

In all of the FIGS. 3 a-3 c embodiments a stepper motor, (not shown), orother functional means, including manual positioning, can be applied toposition polarizer elements during use so that an electromagnetic beampasses through a intended discrete polarizer element. In addition, theshowing of five discrete polarizer (A) (B) (C) (D) and (E) elements ineach of the FIGS. 3 a-3 c is demonstrative and not meant to indicate alimitation. More or less than five discrete polarizer elements can bepresent.

Turning now to FIG. 3 d 1, it is shown that the present invention systemsource of polychromatic radiation (QTH) as in FIG. 1 b can, but notnecessarily, be a system as Claimed in U.S. Pat. No. 6,268,917 to Johs,for providing an output beam (OB) of polychromatic electromagneticradiation which has a relatively broad and flattened intensity vs.wavelength characteristic over a wavelength spectrum (generallyidentified as (LS)), said output beam (OB) of polychromaticelectromagnetic radiation substantially being a comingled composite of aplurality of input beams, ((IB1) and (IB2)), of polychromaticelectromagnetic radiation which individually do not provide asrelatively broad and flattened a intensity vs. wavelength characteristicover said wavelength spectrum, as does said output comingled compositebeam of polychromatic electromagnetic radiation, said system forproviding an output beam of polychromatic electromagnetic radiationwhich has a relatively broad and flattened intensity vs. wavelengthcharacteristic over a wavelength spectrum comprising:

-   -   a. at least a first (SS1) and a second (SS2) source of        electromagnetic radiation, ((IB1) and (IB2) respectively); and    -   b. at least one electromagnetic beam combining (BCM) means        comprising an uncoated plate, (eg. uncoated fused silica or        glass etc. such that transmission characteristics thereof are        determined by angle-of-incidence and polarization state of a        beam of electromagnetic radiation).        The at least one electromagnetic beam combining means (BCM) is        positioned with respect to said first (SS1) and second (SS2)        sources of electromagnetic radiation, (IR1) and (IR2)        respectively), such that a beam of electromagnetic radiation        (IB1) from said first (SS1) source of electromagnetic radiation        passes through said at least one electromagnetic beam combining        means (BCM), and such that a beam of electromagnetic radiation        (IB2) from said second (SS2) source of electromagnetic radiation        reflects from said at least one electromagnetic beam combining        means (BCM) and is comingled with said beam of electromagnetic        radiation (IB1) from said first source (SS1) of polychromatic        electromagnetic radiation which passes through said at least one        electromagnetic beam combining means (BCM). The resultant output        beam of polychromatic electromagnetic radiation (OB) has a        relatively broad and flattened intensity vs. wavelength over a        wavelength spectrum, comprising said comingled composite of a        plurality of input beams of electromagnetic radiation which        individually do not provide such a relatively broad and        flattened intensity vs. wavelength over a wavelength spectrum        characteristic. It is noted that preferred practice provides        that the sources of electromagnetic radiation ((IB1) and (IB2))        each provide a polychromatic output. Also shown in FIG. 3 d 1        are collimating lenses (L1) and (L2) to provide collimated        electromagnetic radiation to the electromagnetic beam combining        means (BCM), from first (SS1) and a second (SS2) source of        polychromatic electromagnetic radiation, ((IB1) and (IB2)        respectively).

FIG. 3 d 1 further demonstrates an optional third source of, preferablypolychromatic, electromagnetic radiation (SS3) and a secondelectromagnetic beam combining means (BCM′). The second electromagneticbeam combining means (BCM′) is positioned with respect to said comingledbeam of polychromatic electromagnetic radiation (OB), (which has arelatively broad and flattened intensity vs. wavelength over awavelength spectrum, comprising wavelengths from sources (SS1) and(SS2), which exits said at least a first electromagnetic beam combiningmeans (BCM)), such that said comingled beam of polychromaticelectromagnetic radiation (OB) passes through said secondelectromagnetic beam combining means (BCM). The second electromagneticbeam combining means (BCM) is positioned with respect to said thirdsource of electromagnetic radiation (SS3) such that a beam ofelectromagnetic radiation from said third source of electromagneticradiation (SS3) reflects from said second electromagnetic beam combiningmeans (BCM) to form a second resultant beam of polychromaticelectromagnetic radiation (OB′).

Further, as described in the Disclosure of the invention Section of thisSpecification, as the polarizer in the present invention spectroscopicellipsometer system remains fixed in position during data acquisition,it is preferable that a source of electromagnetic radiation, and/or apresent Polarizer or Polarization State Generator be positioned orconfigured so as to pass predominately “S” Polarized electromagneticradiation, as referenced to said beam combining system. The reason forthis is that the split between transmission and reflection “S”polarization components is less, as a function of wavelength andelectromagnetic beam angle-of-incidence to said beam combining means,compared to that between the “P” components.

FIG. 3 d 2 shows a Beam Chromatic Shifting and Directing Means (ZCM)which comprises a Silicon Substrate (SI) upon the surface of which ispresent between about 500 and 1500 Angstroms, (nominal 600 or 1200Angstroms), of Silicon Dioxide (SIO2). FIG. 3 d 3 demonstrates theeffect of reflecting the Energy Spectrum provided by a SpectroscopicSource of Electromagnetic Radiation (ZQTH), (see curve (EMI))corresponding to Beam (EMI) in FIG. 3 d 2, and the corresponding ShiftedEnergy Spectrum which results from reflection of said input Spectrum.

It is also generally noted that the present invention spectroscopicellipsometer system can, but not necessarily, utilize Zeiss Diode ArraySpectrometer Systems identified by manufacturer numbers in the group:(MMS1 (300-1150 nm); UV/VIS MMS (190-730 nm); UV MMS (190-400 nm); andIR MMS (900-2400 nm)) as Detector System (DET). Said identified Zeisssystems provide a very compact system comprising a multiplicity ofDetector Elements and provide focusing via a Focusing Element, Slit, andsingle concave holographic grating dispersive optics. However, anyfunctional multi-element spectroscopic Detector arrangement is withinthe scope of the present invention.

FIG. 4 a demonstrates a flow of use of the present invention,electromagnetic beam combining means (BCM) to form a second resultantbeam of polychromatic electromagnetic radiation (OB′) which issubstantially an output beam of polychromatic electromagnetic radiationwhich has an even more relatively broadened and flattened intensity vs.wavelength over a wavelength spectrum comprising said comingledcomposite of a plurality of input beams of electromagnetic radiation,(from sources (SS1), (SS2) and (SS3)), which sources (SS1), (SS2) and(SS3) individually do not provide such a relatively broadened andflattened intensity vs. wavelength over a wavelength spectrumcharacteristic. Note that first or second resultant beam ofpolychromatic electromagnetic radiation (OB) (OB′) in FIG. 3 d 1 can becomprise the source (QTH) in FIG. 1 a., or be combined (LED) outputs.(It is noted that any of said sources (SS1) (SS2) and (SS3) can bepolychromatic electromagnetic radiation sources such as Xenon orDuterium, and Quartz-Halogen lamps, or other suitable source).

A system as shown in FIG. 3 d 1 can also include a pivot(s) (PV) (PV′)to allow the beam combining means (BCM) and/or (BCM′), respectively, tobe rotated. This can be beneficially applied to allow selection of anoptimum angle at which a beam of electromagnetic radiation is caused toreflect therefrom in use. It is noted that the angle at which a beam ofelectromagnetic radiation approaches a beam combining means affects thepercent of an impinging beam which actually reflects therefrom andbecomes part of the output beam (OB), and where a beam sourcepositioning can be changed along with pivoting of a beam combiningmeans, this allows optimum combining of transmitted and reflected beams.Also, pivot with two degrees of rotational freedom can be applied tosimply effect coincidence of transmitted and reflected beams ofelectromagnetic radiation which originate from sources which are fixedin location. and FIG. 4 b demonstrates the flow of a present inventionmethod of calibration of the spectroscopic ellipsometer portion of thepresent invention.

FIGS. 5-11 show Intensity vs. Wavelength for the seven (7)ellipsometrically different samples at each of five (5) imposedpolarization states. Results shown in FIGS. 5-7 respectively, are forSamples identified as 1, 2, 3, 4, 5, 6, and 7, which respectively haveOxide depths atop thereof of, (in Angstroms), 17.50; 103.0; 193.0;508.0; 1318.0; 4817.0 and 9961.0.

(Note, the data in FIGS. 5-11 were obtained utilizing a single source ofelectromagnetic radiation which had a number of polarization stateimposed thereupon by means as shown in FIGS. 3 a-3 c being placed into abeam of electromagnetic radiation. However, the same approachdemonstrated is directly applicable to the case where a sequence ofdifferent polarization states are provided by different discretesources, each of which provides a different polarization state asdemonstrated in FIG. 1 b).

FIGS. 12 & 13 show PSI and DELTA values obtained for samples with thin(native), and thick, (9961 Angstrom), layers of Oxide thereupon. Allresults were obtained by fitting a mathematical model of the samplesystem and the spectroscopic ellipsometer system by regression ontoexperimental data.

Having hereby disclosed the subject matter of the present invention, itshould be obvious that many modifications, substitutions, and variationsof the present invention are possible in view of the teachings. It istherefore to be understood that the invention may be practiced otherthan as specifically described, and should be limited in its breadth andscope only by the Claims.

1. A spectroscopic ellipsometer system comprising: a source of apolychromatic beam of electromagnetic radiation; a stage for supportinga sample system; a multi-element spectroscopic detector system; saidspectroscopic ellipsometer system further comprising: at least twopolarizers (P1) (P2), which remain fixed in position during dataacquisition, said polarizers (P1) (P2) being in the source of a beam ofpolychromatic electromagnetic radiation, before the stage for supportinga sample system; an analyzer, which remains fixed in position duringdata acquisition, after said stage for supporting a sample system andbefore said multi-element spectroscopic detector system; and at leastone means for discretely, sequentially, modifying a polarization stateof a beam of electromagnetic radiation provided by said source of a beamof polychromatic electromagnetic radiation through a plurality ofpolarization states, said means for discretely, sequentially, modifyinga polarization state of a beam of electromagnetic radiation provided bysaid source of a beam of polychromatic electromagnetic radiation througha plurality of polarization states being present at least one locationselected from the group consisting of: between said polarizer and saidstage for supporting a sample system; and between said stage forsupporting a sample system and said analyzer; and positioned so thatsaid beam of electromagnetic radiation transmits therethrough in use;said ellipsometer system being configured such that a polychromatic beamof electromagnetic radiation provided by said source thereof is directedto interact with a sample system present on said stage for supporting asample system; said ellipsometer system being distinguished in that saidsource of a beam of polychromatic electromagnetic radiation comprises:a. at least a first (S1) and a second (S2) source of polychromaticelectromagnetic radiation beams, (B1) and (B2) respectively, which havesaid polarizers, (P1) and (P2) respectively, associated therewith; andb. at least one electromagnetic beam combining (BC1) means comprising anuncoated plate with transmission characteristics that are determined byangle-of-incidence and polarization state of a beam of electromagneticsuch that in use one of said (B1) and (B2) beams after passing throughits associated polarizer (P1) (P2), passes through said beam combining(BC1) means, and the other thereof, after passing through its associatedpolarizer (P2) (P1), reflects from said beam combining means (BC1), suchthat a polarized beam containing wavelengths from at least one of said(S1) and (S2) sources emerges from said beam combining (BC1) means andis directed to interact with said sample system present on said stagefor supporting a sample system; said at least first (S1) and second (S2)sources being separately energizable.
 2. A spectroscopic ellipsometersystem as in claim 1 which further comprises: an electromagnetic beamchromatic shifting and directing means (ZCM) for use in reflectivelydirecting a spectroscopic beam of electromagnetic radiation whilede-emphasizing intensity in visual wavelengths and while simultaneouslyemphasising both IR and UV wavelength intensities, said electromagneticbeam chromatic shifting and directing means comprising a siliconsubstrate with between 500 and 1500 Angstroms of silicon dioxidesubstantially uniformly present on a reflective surface thereof; saidelectromagnetic beam chromatic shifting and directing means (ZCM) beingother than said sample system and positioned so as to interact with saidpolarized beam containing wavelengths from at least one of said (S1) and(S2) sources which emerges from said beam combining (BC1) means beforesaid Polarized beam enters said said multi-element spectroscopicdetector system.
 3. A spectroscopic ellipsometer system comprising asource of a polychromatic beam of electromagnetic radiation whichcomprises: a. at least a first S1) and a second (S2) source ofpolychromatic electromagnetic radiation beams, (B1) and (B2)respectively, each of which has a separate polarizer, (P1) and (P2)respectively, associated therewith; and b. at least a firstelectromagnetic beam combining (BC1) means comprising an uncoated platewith transmission characteristics that are determined byangle-of-incidence and polarization state of a beam of electromagneticradiation; such that in use at least one of said (B1) and (B2) beams,after passing through its associated polarizer (P1) (P2), passes throughsaid first beam combining (BC1) means, and the other thereof, afterpassing through its associated polarizer (P2) (P1), reflects from saidfirst beam combining means (BC1), such that a polarized beam ofpolychromatic electromagnetic radiation containing wavelengths from atleast one of said (S1) and (S2) sources emerges from said first beamcombining (BC1) means and is directed to interact with said samplesystem present on said stage for supporting a sample system; said atleast first (S1) and second (S2) sources being separately energizable;said spectroscopic ellipsometer system further comprising: a stage forsupporting a sample system; a multi-element spectroscopic detectorsystem; an analyzer, which remains fixed in position during dataacquisition, after said stage for supporting a sample system and beforesaid multi-element spectroscopic detector system; and at least one meansfor discretely, sequentially, modifying a polarization state of a beamof electromagnetic radiation provided by said source of polychromaticelectromagnetic radiation through a plurality of polarization states,said means for discretely, sequentially, modifying a polarization stateof a beam of electromagnetic radiation provided by said source means ofpolychromatic electromagnetic radiation through a plurality ofpolarization states being present at at least one location selected fromthe group consisting of: between said polarizer and said stage forsupporting a sample system; and between said stage for supporting asample system and said analyzer; and positioned so that said beam ofelectromagnetic radiation transmits therethrough in use; saidellipsometer system being configured such that a polychromatic beam ofelectromagnetic radiation provided by said source of a polychromaticelectromagnetic radiation is directed to interact with a sample systempresent on said stage for supporting a sample system, reflect therefromand enter said multi-element spectroscopic detector system.
 4. Aspectroscopic ellipsometer system as in claim 3 which further comprises:an electromagnetic beam chromatic shifting and directing means (ZCM) foruse in reflectively directing a spectroscopic beam of electromagneticradiation while de-emphasizing intensity in visual wavelengths and whilesimultaneously emphasising both IR and UV wavelength intensities, saidelectromagnetic beam chromatic shifting and directing means comprising asilicon substrate with between 500 and 1500 Angstroms of silicon dioxidesubstantially uniformly present on a reflective surface thereof; saidelectromagnetic beam chromatic shifting and directing means (ZCM) beingother than said sample system and positioned so as to interact with saidpolarized beam containing wavelengths from at least one of said (S1) and(S2) sources which emerge from said first beam combining (BC1) meansbefore said polarized beam enters said multi-element spectroscopicdetector system.
 5. A spectroscopic ellipsometer system as in claim 3which, between said beam combining means (BC1) and said sample system,further comprises: a second beam combining means (BC2) through whichwavelengths from at least one of said (S1) and (S2) sources which emergefrom said first beam combining (BC1) means also pass; and which alsofurther comprises: a. at least a third (S3) and a forth (S4) source ofpolychromatic electromagnetic radiation beams, (B3) and (B4)respectively, each of which has a separate polarizer, (P3) and (P4)respectively, associated therewith; and b. at least a third additionalelectromagnetic beam combining (BC3) means comprising an uncoated platewith transmission characteristics that are determined byangle-of-incidence and polarization state of a beam of electromagneticradiation; such that in use at least one of said (B3) and (B4) beams,after passing through its associated polarizer (P3) (P4), passes throughsaid second beam combining (BC3) means, and the other thereof, afterpassing through its associated polarizer (P4) (P3), reflects from saidthird beam combining means (BC3), such that a polarized beam ofpolychromatic electromagnetic radiation containing wavelengths from atleast one of said (S3) and (S4) sources emerges from said third beamcombining (BC3) means and is directed to interact with said samplesystem present on said stage for supporting a sample system byreflecting from said second beam combining (BC2) means; said at leastfirst (S3) and second (S4) sources being separately energizable; suchthat wavelengths from at least one of said (S1) (S2) (S3) and (S4)sources is directed to interact with said sample system present on saidstage for supporting a sample system, reflect therefrom and enter saidmulti-element spectroscopic detector system.
 6. A spectroscopicellipsometer system as in claim 5 which further comprises: anelectromagnetic beam chromatic shifting and directing means (ZCM) foruse in reflectively directing a spectroscopic beam of electromagneticradiation while de-emphasizing intensity in visual wavelengths and whilesimultaneously emphasising both IR and UV wavelength intensities, saidelectromagnetic beam chromatic shifting and directing means comprising asilicon substrate with between 500 and 1500 Angstroms of silicon dioxidesubstantially uniformly present on a reflective surface thereof; saidelectromagnetic beam chromatic shifting and directing means (ZCM) beingother than said sample system and positioned so as to interact with saidpolarized beam containing wavelengths from at least one of said (S1)(S2) (S3) and (S4) sources which emerge from said second beam combining(BC2) means before said polarized beam enters said multi-elementspectroscopic detector system.